Review and prospects of Mn-based spinel compounds as cathode materials for lithium-ion batteries

被引：43
作者：
Dou, Shumei [1 ]
机构：
[1] Baoji Univ Arts & Sci, Coll Chem & Chem Engineer, Shaanxi Key Lab Phytochem, Baoji 721013, Shaanxi, Peoples R China
来源：
IONICS | 2015年 / 21卷 / 11期
关键词：
Li-ion batteries; Spinels; Cathodes; Electrochemical promotion; Electrochemical characterizations; HIGH-RATE CAPABILITY; COATED LINI0.5MN1.5O4 SPINEL; HIGH-ENERGY DENSITY; TEMPERATURE CYCLING STABILITY; NICKEL MANGANESE OXIDE; CORE-SHELL STRUCTURE; LI-ION; LIMN2O4; CATHODE; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS;
D O I：
10.1007/s11581-015-1545-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Lithium-ion batteries are one of the most promising electrochemical power sources to be widely used in portable electronics, electric vehicles, and stationary energy storage systems. Mn-based spinel compounds have been intensively investigated as cathode materials for lithium-ion batteries due to their low cost, high safety, and excellent cycling stability. This work reviews the latest advances in exploration and development of Mn-based spinel compounds, including LiMn2O4 and LiNi0.5Mn1.5O4, as high performance cathode materials for lithium-ion batteries. The relationship between the electrochemical properties and composition, structure, morphology are summarized and analyzed. The prospects of the Mn-based spinel compounds as cathode materials for lithium-ion batteries are also looked forward to.
引用
收藏
页码：3001 / 3030
页数：30
相关论文
共 163 条
[21]   Porous LiMn2O4 nanorods with durable high-rate capability for rechargeable Li-ion batteries [J].
Cheng, Fangyi ;
Wang, Hongbo ;
Zhu, Zhiqiang ;
Wang, Yan ;
Zhang, Tianran ;
Tao, Zhanliang ;
Chen, Jun .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3668-3675
[22]   Functional Materials for Rechargeable Batteries [J].
Cheng, Fangyi ;
Liang, Jing ;
Tao, Zhanliang ;
Chen, Jun .
ADVANCED MATERIALS, 2011, 23 (15) :1695-1715
[23]   A polymer electrolyte-skinned active material strategy toward high-voltage lithium ion batteries: a polyimide-coated LiNi0.5Mn1.5O4 spinel cathode material case [J].
Cho, Ju-Hyun ;
Park, Jang-Hoon ;
Lee, Myeong-Hee ;
Song, Hyun-Kon ;
Lee, Sang-Young .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (05) :7124-7131
[24]   Effects of CeO2 coating uniformity on high temperature cycle life performance of LiMn2O4 [J].
Cho, Min-Young ;
Roh, Kwang-Chul ;
Park, Sun-Min ;
Lee, Jae-Won .
MATERIALS LETTERS, 2011, 65 (13) :2011-2014
[25]   Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors [J].
Choi, Nam-Soon ;
Chen, Zonghai ;
Freunberger, Stefan A. ;
Ji, Xiulei ;
Sun, Yang-Kook ;
Amine, Khalil ;
Yushin, Gleb ;
Nazar, Linda F. ;
Cho, Jaephil ;
Bruce, Peter G. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (40) :9994-10024
[26]   Surface stabilized LiNi0.5Mn1.5O4 cathode materials with high-rate capability and long cycle life for lithium ion batteries [J].
Chong, Jin ;
Xun, Shidi ;
Song, Xiangyun ;
Liu, Gao ;
Battaglia, Vincent S. .
NANO ENERGY, 2013, 2 (02) :283-293
[27]   Effect of Ca,Mg-ions on the properties of LiCo0.9M0.1PO4/graphitic carbon composites [J].
Dimesso, Lucangelo ;
Becker, Dirk ;
Spanheimer, Christina ;
Jaegermann, Wolfram .
PROGRESS IN SOLID STATE CHEMISTRY, 2014, 42 (04) :184-190
[28]   Preparation and performance comparison of LiMn2O3.95Br0.05 and LiMn2O3.95Br0.05/SiO2 cathode materials for lithium-ion battery [J].
Dong, Zhifang ;
Huang, Yudai ;
Jia, Dianzeng ;
Guo, Zaiping .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2011, 15 (04) :725-730
[29]   Review and prospect of layered lithium nickel manganese oxide as cathode materials for Li-ion batteries [J].
Dou, Shumei .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2013, 17 (04) :911-926
[30]   Lithium Insertion in Nanostructured TiO2(B) Architectures [J].
Dylla, Anthony G. ;
Henkelman, Graeme ;
Stevenson, Keith J. .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (05) :1104-1112
12345678910