Review and prospects of Mn-based spinel compounds as cathode materials for lithium-ion batteries

被引：43
作者：
Dou, Shumei [1 ]
机构：
[1] Baoji Univ Arts & Sci, Coll Chem & Chem Engineer, Shaanxi Key Lab Phytochem, Baoji 721013, Shaanxi, Peoples R China
来源：
IONICS | 2015年 / 21卷 / 11期
关键词：
Li-ion batteries; Spinels; Cathodes; Electrochemical promotion; Electrochemical characterizations; HIGH-RATE CAPABILITY; COATED LINI0.5MN1.5O4 SPINEL; HIGH-ENERGY DENSITY; TEMPERATURE CYCLING STABILITY; NICKEL MANGANESE OXIDE; CORE-SHELL STRUCTURE; LI-ION; LIMN2O4; CATHODE; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS;
D O I：
10.1007/s11581-015-1545-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Lithium-ion batteries are one of the most promising electrochemical power sources to be widely used in portable electronics, electric vehicles, and stationary energy storage systems. Mn-based spinel compounds have been intensively investigated as cathode materials for lithium-ion batteries due to their low cost, high safety, and excellent cycling stability. This work reviews the latest advances in exploration and development of Mn-based spinel compounds, including LiMn2O4 and LiNi0.5Mn1.5O4, as high performance cathode materials for lithium-ion batteries. The relationship between the electrochemical properties and composition, structure, morphology are summarized and analyzed. The prospects of the Mn-based spinel compounds as cathode materials for lithium-ion batteries are also looked forward to.
引用
收藏
页码：3001 / 3030
页数：30
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