Tunable Metallogels Based on Bifunctional Ligands: Precursor Metallogels, Spinel Oxides, Dye and CO2 Adsorption

被引:29
作者
Alam, Noohul [1 ]
Sarma, Debajit [1 ]
机构
[1] Indian Inst Technol Patna, Dept Chem, Bihta 801106, Bihar, India
关键词
METAL-ORGANIC FRAMEWORKS; SELECTIVE REMOVAL; FACILE SYNTHESIS; REDOX CHEMISTRY; ANODE MATERIALS; BATTERY; PERFORMANCE; EFFICIENT; COPPER; LI;
D O I
10.1021/acsomega.0c01710
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A semisolid gel material is a gift of serendipity via various chemical interactions, and metal incorporation (metallogels) imparts diverse functional properties. In this work, we have synthesized four metallogels from tetrapodal and hexapodal carboxylic acid/amide-based low-molecular-weight gelators with Ni(II) and Cu(II) salts. These metallogels can be tuned to be a low-temperature precursor of porous spinel oxides. These xerogels exhibit impressive water soluble dye and carbon dioxide adsorption, which coupled with the tunability and facile synthesis of porous spinel oxides underscores their potential in environmental remediation and energy applications.
引用
收藏
页码:17356 / 17366
页数:11
相关论文
共 77 条
[1]  
Abdallah DJ, 2000, ADV MATER, V12, P1237
[2]   Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by maghemite nanoparticles [J].
Afkhami, Abbas ;
Moosavi, Razieh .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 174 (1-3) :398-403
[3]   Fe(III) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor [J].
Aiyappa, Harshitha Barike ;
Saha, Subhadeep ;
Wadge, Pritish ;
Banerjee, Rahul ;
Kurungot, Sreekumar .
CHEMICAL SCIENCE, 2015, 6 (01) :603-607
[4]  
Ajayaghosh A., 2007, ANGEW CHEM, V119, P6376
[5]   Copper-based hydrogels with dicarboxylate spacer ligands for selective carbon dioxide separation applications [J].
Al-Dossary, Mona ;
Padhy, Harihara ;
Xu, Feng ;
Behzad, Ali R. ;
el Tall, Omar ;
Rothenberger, Alexander .
NEW JOURNAL OF CHEMISTRY, 2018, 42 (22) :18242-18251
[6]   Novel scalable synthesis of highly conducting and robust PEDOT paper for a high performance flexible solid supercapacitor [J].
Anothumakkool, Bihag ;
Soni, Roby ;
Bhange, Siddheshwar N. ;
Kurungot, Sreekumar .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (04) :1339-1347
[7]   Facile coprecipitation synthesis of nickel doped copper oxide nanocomposite as electrocatalyst for methanol electrooxidation in alkaline solution [J].
Arunachalam, Prabhakarn ;
Nagarani, S. ;
Prasad, Saradh ;
AlSalhi, Mohamad S. ;
Al-Mayouf, Abdullah M. ;
Moydeen, Meera A. ;
Ganapathy, Sasikala .
MATERIALS RESEARCH EXPRESS, 2018, 5 (01)
[8]   Redox chemistry of a binary transition metal oxide (AB2O4): a study of the Cu2+/Cu0 and Fe3+/Fe0 interconversions observed upon lithiation in a CuFe2O4 battery using X-ray absorption spectroscopy [J].
Cama, Christina A. ;
Pelliccione, Christopher J. ;
Brady, Alexander B. ;
Li, Jing ;
Stach, Eric A. ;
Wang, Jiajun ;
Wang, Jun ;
Takeuchi, Esther S. ;
Takeuchi, Kenneth J. ;
Marschilok, Amy C. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (25) :16930-16940
[9]   Unprecedented Acid-Promoted Polymerization and Gelation of Acrylamide: A Serendipitous Discovery [J].
Chan, Siew Yin ;
Goh, Shermin S. ;
Dou, Qingqing ;
Chan, Benjamin Qi Yu ;
Choo, Wee Sim ;
Young, David James ;
Loh, Xian Jun .
CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (14) :1797-1804
[10]   Efficient and Selective Removal of Dyes Using Imidazolium-Based Supramolecular Gels [J].
Cheng, Ni ;
Hu, Qiongzheng ;
Guo, Yongxian ;
Wang, Yong ;
Yu, Li .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (19) :10258-10265