Nanoscale Atoms in Solid-State Chemistry

被引：210

作者：

Roy, Xavier ^{[1
]}

Lee, Chul-Ho ^{[1
,2
]}

Crowther, Andrew C. ^{[3
]}

Schenck, Christine L. ^{[1
]}

Besara, Tiglet ^{[4
]}

Lalancette, Roger A. ^{[6
]}

Siegrist, Theo ^{[4
,5
]}

Stephens, Peter W. ^{[7
]}

Brus, Louis E. ^{[1
]}

Kim, Philip ^{[2
]}

Steigerwald, Michael L. ^{[1
]}

Nuckolls, Colin ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

[2] Columbia Univ, Dept Phys, New York, NY 10027 USA

[3] Columbia Univ Barnard Coll, Dept Chem, New York, NY 10027 USA

[4] Florida State Univ, NHMFL, Tallahassee, FL 32310 USA

[5] Florida A&M Univ FSU Coll Engn, Dept Chem & Biomed Engn, Tallahassee, FL 32310 USA

[6] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

[7] SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA

来源：

SCIENCE | 2013年 / 341卷 / 6142期

基金：

新加坡国家研究基金会; 加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

CRYSTAL-STRUCTURE; PEROVSKITES; FULLERIDES; SALTS;

D O I：

10.1126/science.1236259

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

We describe a solid-state material formed from binary assembly of atomically precise molecular clusters. [Co6Se8(PEt3)(6)][C-60](2) and [Cr6Te8(PEt3)(6)][C-60](2) assembled into a superatomic relative of the cadmium iodide (CdI2) structure type. These solid-state materials showed activated electronic transport with activation energies of 100 to 150 millielectron volts. The more reducing cluster Ni9Te6(PEt3)(8) transferred more charge to the fullerene and formed a rock-salt-related structure. In this material, the constituent clusters are able to interact electronically to produce a magnetically ordered phase at low temperature, akin to atoms in a solid-state compound.

引用

页码：157 / 160

页数：4

共 20 条

[1]

Auyeung E, 2012, NAT NANOTECHNOL, V7, P24, DOI [10.1038/NNANO.2011.222, 10.1038/nnano.2011.222]

[2] ANTIPEROVSKITE STRUCTURE WITH TERNARY TETRATHIAFULVALENIUM SALTS - CONSTRUCTION, DISTORTION, AND ANTIFERROMAGNETIC ORDERING [J].