Tribenzyltin(IV) chloride Thiosemicarbazones: Novel Single Source Precursors for Growth of SnS Thin Films

被引:55
作者
Bade, Balasaheb P. [1 ]
Garje, Shivram S. [1 ]
Niwate, Yogesh S. [1 ]
Afzaal, Mohammad [2 ,3 ]
O'Brien, Paul [2 ,3 ]
机构
[1] Univ Bombay, Dept Chem, Bombay 400098, Maharashtra, India
[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[3] Univ Manchester, Sch Mat, Manchester M13 9PL, Lancs, England
基金
英国工程与自然科学研究理事会;
关键词
Single-source precursors; Thin films; Tin sulfide; Tin thiosemicarbazones;
D O I
10.1002/cvde.200806687
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Tin sulfide (SnS) thin films are deposited using simple tin thiosemicarbazone complexes of the type Bz(3)SnCl(L) (L = thiosemicarbazones of salicylaldehye and 4-chlorobenzaldehyde). Thin films are deposited using aerosol-assisted (AA) CVD in the range 375-475 degrees C. X-ray diffraction (XRD) shows the formation of SnS regardless of growth temperature and precursor type. Scanning electron microscope (SEM) images show that the films have wafer-like morphology, and the growth temperatures do not have a profound effect on morphology.
引用
收藏
页码:292 / 295
页数:4
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