Geology, Fluid Inclusion Characteristics and H-O-C Isotopes of Large Lijiagou Pegmatite Spodumene Deposit in Songpan-Garze Fold Belt, Eastern Tibet: Implications for ore Genesis

The large, newly discovered Lijiagou pegmatite spodumene deposit, is located southeast of the Ke'eryin pegmatite ore field, in the central Songpan-Garze Fold Belt (SGFB), Eastern Tibet. The Lijiagou albite spodumene pegmatites are unzoned, granite-pegmatites of the subtype LCT (Lithium, Cesium, and Tantalum) and consist of medium-to coarse-grained spodumene, lepidolite, microcline, albite, quartz, muscovite, and accessory amounts of beryl, cassiterite, columbite-tantalite and zircon. Secondary fluid inclusions in quartz and spodumene include two-phase aqueous inclusions (V + L), mono-phase vapor inclusions (V); three-phase CO2-rich CO2-H2O inclusions (CO2 + V + L) and less abundant liquid inclusions (L). The homogenization temperature of the fluid inclusions are low (257.3 to 204.3 degrees C in early stage, 250.3 to 199.6 degrees C in middle stage, 218.7 to 200.6 degrees C in late stage). Fluid inclusions were formed during the long cooling period from the temperature of the pegmatite emplacement. Liquid-vapor-gas boiling was extensive during the middle and late stages. The salinity of the corresponding stages are 15.4 to 13.0 wt.% NaCl equiv., 12.5 to 9.1 wt.% NaCl equiv. and 9.8 to 7.8 wt.% NaCl equiv., respectively. delta O-18 values of fluid are 7.2 to 5.2 parts per thousand, 5.6 to 3.9 parts per thousand and 2.7 to -0.2 parts per thousand from early to late stages; and delta D range from -75.1 to -76.8 parts per thousand, -59.0 to -73.5 parts per thousand and -61.6 to -85.5 parts per thousand respectively. The delta C-13 of CO2 values are -5.6 to -6.6 parts per thousand, -8.5 to -19.9 parts per thousand, -11.8 to -18.7 parts per thousand from early to late stages, suggesting that CO2 in the fluids were probably sourced from a magmatic system, possibly with some mixing of CO2 dissolved in groundwater. dD and delta O-18 values of fluid indicate that the fluids were originally magmatic water and mixed with some meteoric water in late stage. The magma evolution sequence in the Ke'eryin orefield, from the central two-mica granite through the Lijiagou deposit out to the distal pegmatites, with the ages gradually decreasing, indicates that the Ke'eryin complex rocks are the product of multistage magmatic activity. The large Lijiagou spodumene deposit is a typical magmatic, fractional crystallization related pegmatite deposit.