A cobalt(II) metal-organic framework with all-cis 1,2,3,4,5,6-cyclohexanehexacarboxylate ligand: Synthesis, structure, and magnetic properties

被引：0
作者：
Cu, Zhi-Guo [1 ,2 ,3 ]
Pang, Chun-Yan [1 ]
Li, Zaijun [1 ]
Xiao, Hong-Ping [4 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[4] Wenzhou Univ, Sch Chem & Mat Engn, Wenzhou 325027, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 24卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; all-cis cyclohexanehexacarboxylate; Three-dimensional; Magnetic properties; CRYSTAL-STRUCTURES; CARBOXYLATE; CD(II);
D O I：
10.1016/j.inoche.2012.07.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new three-dimensional metal-organic framework, [Co-3(cis-CHHC)(H2O)(8)](n)center dot 5nH(2)O (1), was synthesized by assembling Co(II) ion and all-cis 1,2,3,4.5,6-cyclohexanehexacarboxylate (cis-CHHC) ligand in hydrothermal condition. X-ray crystallography reveals that each cis-CHHC ligand connects six Co(II) atoms, and each Co(II) atom is linked to two cis-CHHC ligands, leading to a 3D structure with channels filled with lattice water molecules. Magnetic analysis of 1 indicates that the antiferromagnetic coupling dominates the magnetic properties. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：237 / 240
页数：4
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