A cobalt(II) metal-organic framework with all-cis 1,2,3,4,5,6-cyclohexanehexacarboxylate ligand: Synthesis, structure, and magnetic properties

被引：0

作者：

Cu, Zhi-Guo ^{[1
,2
,3
]}

Pang, Chun-Yan ^{[1
]}

Li, Zaijun ^{[1
]}

Xiao, Hong-Ping ^{[4
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[3] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[4] Wenzhou Univ, Sch Chem & Mat Engn, Wenzhou 325027, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 24卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; all-cis cyclohexanehexacarboxylate; Three-dimensional; Magnetic properties; CRYSTAL-STRUCTURES; CARBOXYLATE; CD(II);

D O I：

10.1016/j.inoche.2012.07.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new three-dimensional metal-organic framework, [Co-3(cis-CHHC)(H2O)(8)](n)center dot 5nH(2)O (1), was synthesized by assembling Co(II) ion and all-cis 1,2,3,4.5,6-cyclohexanehexacarboxylate (cis-CHHC) ligand in hydrothermal condition. X-ray crystallography reveals that each cis-CHHC ligand connects six Co(II) atoms, and each Co(II) atom is linked to two cis-CHHC ligands, leading to a 3D structure with channels filled with lattice water molecules. Magnetic analysis of 1 indicates that the antiferromagnetic coupling dominates the magnetic properties. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：237 / 240

页数：4

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