One-step MOF-derived Co/Co9S8 nanoparticles embedded in nitrogen, sulfur and oxygen ternary-doped porous carbon: an efficient electrocatalyst for overall water splitting

被引:87
作者
Du, Jiao [1 ]
Wang, Rui [1 ]
Lv, Ya-Ru [1 ]
Wei, Yong-Li [1 ]
Zang, Shuang-Quan [1 ]
机构
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORK; EXCELLENT BIFUNCTIONAL ELECTROCATALYSTS; REDUCTION; CO; CATALYSTS; ELECTRODE;
D O I
10.1039/c9cc00196d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Co/Co9S8 nanoparticles encapsulated in a N, S, and O ternary-doped carbon matrix were synthesized utilizing a Co-NSOMOF as a single precursor, and they exhibited excellent bifunctional electrocatalytic activity for the OER and HER. Impressively, the water splitting cell exhibited a low cell voltage of 1.56 V at 10 mA cm(-2). The high performances were attributed to the synergistic effect and the protection of multi-heteroatom doped carbon shells for active Co/Co9S8 nanoparticles.
引用
收藏
页码:3203 / 3206
页数:4
相关论文
共 30 条
[1]   Nitrogen and Sulfur Codoped Graphene: Multifunctional Electrode Materials for High-Performance Li-Ion Batteries and Oxygen Reduction Reaction [J].
Ai, Wei ;
Luo, Zhimin ;
Jiang, Jian ;
Zhu, Jianhui ;
Du, Zhuzhu ;
Fan, Zhanxi ;
Xie, Linghai ;
Zhang, Hua ;
Huang, Wei ;
Yu, Ting .
ADVANCED MATERIALS, 2014, 26 (35) :6186-+
[2]   3D Co-N-doped hollow carbon spheres as excellent bifunctional electrocatalysts for oxygen reduction reaction and oxygen evolution reaction [J].
Cai, Shichang ;
Meng, Zihan ;
Tang, Haolin ;
Wang, Yi ;
Tsiakaras, Panagiotis .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 217 :477-484
[3]   Cobalt sulfide/N,S codoped porous carbon core-shell nanocomposites as superior bifunctional electrocatalysts for oxygen reduction and evolution reactions [J].
Chen, Binling ;
Li, Rong ;
Ma, Guiping ;
Gou, Xinglong ;
Zhu, Yanqiu ;
Xia, Yongde .
NANOSCALE, 2015, 7 (48) :20674-20684
[4]   Metal-organic framework-derived porous materials for catalysis [J].
Chen, Yu-Zhen ;
Zhang, Rui ;
Jiao, Long ;
Jiang, Hai-Long .
COORDINATION CHEMISTRY REVIEWS, 2018, 362 :1-23
[5]   From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis [J].
Chen, Yu-Zhen ;
Wang, Chengming ;
Wu, Zhen-Yu ;
Xiong, Yujie ;
Xu, Qiang ;
Yu, Shu-Hong ;
Jiang, Hai-Long .
ADVANCED MATERIALS, 2015, 27 (34) :5010-5016
[6]   Ultrastable hydrogen evolution electrocatalyst derived from phosphide postmodified metal-organic frameworks [J].
Cheng, Yuanhui ;
Guo, Jianing ;
Huang, Yan ;
Liao, Zhijian ;
Xiang, Zhonghua .
NANO ENERGY, 2017, 35 :115-120
[7]   Two-Dimensional N,S-Codoped Carbon/Co9S8 Catalysts Derived from Co(OH)2 Nanosheets for Oxygen Reduction Reaction [J].
Fu, Shaofang ;
Zhu, Chengzhou ;
Song, Junhua ;
Feng, Shuo ;
Du, Dan ;
Engelhard, Mark H. ;
Xiao, Dongdong ;
Li, Dongsheng ;
Lin, Yuehe .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (42) :36755-36761
[8]   X-ray Photoelectron Spectroscopy Analysis of Hydrotreated Athabasca Asphaltenes [J].
Guzman, Hector J. ;
Isquierdo, Fernanda ;
Carbognani, Lante ;
Vitale, Gerardo ;
Scott, Carlos E. ;
Pereira-Almao, Pedro .
ENERGY & FUELS, 2017, 31 (10) :10706-10717
[9]   Design of a porous cobalt sulfide nanosheet array on Ni foam from zeolitic imidazolate frameworks as an advanced electrode for supercapacitors [J].
Han, Xue ;
Tao, Kai ;
Wang, Ding ;
Han, Lei .
NANOSCALE, 2018, 10 (06) :2735-2741
[10]   Multifunctional Carbon-Based Metal-Free Electrocatalysts for Simultaneous Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution [J].
Hu, Chuangang ;
Dai, Liming .
ADVANCED MATERIALS, 2017, 29 (09)