Synthesis and Reactivity of Metal Complexes with Acyclic (Amino)-(Ylide)Carbene Ligands

被引：17
作者：
Gonzalez-Fernandez, Elisa [1 ]
Rust, Joerg [1 ]
Alcarazo, Manuel [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 43期
基金：
欧洲研究理事会;
关键词：
acyclic carbenes; gold; ligand design; transmetalation; ylides; N-HETEROCYCLIC CARBENES; ONE-POT SYNTHESIS; X-RAY; FUNCTIONALIZED ISOCYANIDES; GOLD; YLIDES; PLATINUM(II); CRYSTAL;
D O I：
10.1002/anie.201305311
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron-rich olefins. Their ability to form bimetallic species and to act as ligand-transfer reagents has also been established. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11392 / 11395
页数：4
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