Biogenic flower-shaped Au-Pd nanoparticles: synthesis, SERS detection and catalysis towards benzyl alcohol oxidation

被引：71
作者：
Sun, Daohua [1 ]
Zhang, Genlei [1 ]
Jiang, Xinde [1 ]
Huang, Jiale [1 ]
Jing, Xiaolian [1 ]
Zheng, Yanmei [1 ]
He, Jing [1 ]
Li, Qingbiao [1 ]
机构：
[1] Xiamen Univ, Dept Chem & Biochem Engn, Coll Chem & Chem Engn, Fujian Prov Key Lab Chem Biol, Xiamen 361005, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 06期
关键词：
ENHANCED RAMAN-SCATTERING; AG ALLOY NANOPARTICLES; LIQUID-PHASE OXIDATION; BIMETALLIC NANOPARTICLES; EXTRACELLULAR BIOSYNTHESIS; SHELL NANOPARTICLES; GOLD NANOPARTICLES; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; GREEN SYNTHESIS;
D O I：
10.1039/c3ta13922k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
similar to 40 nm flower-shaped Au-Pd bimetallic nanoparticles were prepared in a facile and eco-friendly way based on the simultaneous bioreduction of HAuCl4 and Na2PdCl4 with ascorbic acid and Cacumen Platycladi leaf extract at room temperature. Characterization techniques, such as transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction, were employed to confirm that the as-synthesized nanoparticles were alloys. The obtained flower-shaped Au-Pd alloy nanoparticles exhibited an excellent surface enhanced Raman spectroscopic activity with rhodamine 6G and efficient catalytic ability for the oxidation of benzyl alcohol to benzaldehyde.
引用
收藏
页码：1767 / 1773
页数：7
相关论文
共 39 条
  • [1] Extracellular biosynthesis of silver nanoparticles using the fungus Fusarium oxysporum
    Ahmad, A
    Mukherjee, P
    Senapati, S
    Mandal, D
    Khan, MI
    Kumar, R
    Sastry, M
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2003, 28 (04) : 313 - 318
  • [2] [Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200603068
  • [3] [Anonymous], ANGEW CHEM INT ED
  • [4] High-yield synthesis of multi-branched urchin-like gold nanoparticles
    Bakr, Osman M.
    Wunsch, Benjamin H.
    Stellacci, Francesco
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (14) : 3297 - 3301
  • [5] Solvent-free aerobic oxidation of benzyl alcohol over Pd monometallic and Au-Pd bimetallic catalysts supported on SBA-16 mesoporous molecular sieves
    Chen, Yuanting
    Lim, Huimin
    Tang, Qinghu
    Gao, Yating
    Sun, Ting
    Yan, Qingyu
    Yang, Yanhui
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 380 (1-2) : 55 - 65
  • [6] Synthesis of NiAu alloy and core-shell nanoparticles in water-in-oil microemulsions
    Chiu, Hsin-Kai
    Chiang, I-Chen
    Chen, Dong-Hwang
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2009, 11 (05) : 1137 - 1144
  • [7] Synthesis of Ag/Pd nanoparticles and their low-temperature alloying within thermally evaporated fatty acid films
    Damle, C
    Kumar, A
    Sastry, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (02) : 297 - 302
  • [8] Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts
    Enache, DI
    Edwards, JK
    Landon, P
    Solsona-Espriu, B
    Carley, AF
    Herzing, AA
    Watanabe, M
    Kiely, CJ
    Knight, DW
    Hutchings, GJ
    [J]. SCIENCE, 2006, 311 (5759) : 362 - 365
  • [9] Nanoalloys: From theory to applications of alloy clusters and nanoparticles
    Ferrando, Riccardo
    Jellinek, Julius
    Johnston, Roy L.
    [J]. CHEMICAL REVIEWS, 2008, 108 (03) : 845 - 910
  • [10] Discrimination of active palladium sites in catalytic liquid-phase oxidation of benzyl alcohol
    Ferri, Davide
    Mondelli, Cecilia
    Krumeich, Frank
    Baiker, Alfons
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (46) : 22982 - 22986
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