Activation of C-F bonds in ionic liquids catalyzed by nickel complex compounds

被引：4

作者：

Prikhod'ko, S. A. ^{[1
]}

Adonin, N. Yu ^{[1
]}

Parmon, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

metal complex catalysis; activation of C-F bond; ionic liquids; acet(pentafluoroanilide); nickel complexes; 2,2 '-bipyridine; 1,10-phenanthroline; hydrodefluorination; 3,4,5-trifluoroaniline; organofluorine compounds; CROSS-COUPLING REACTIONS; HECK REACTION; ARYL HALIDES; HIGHLY EFFICIENT; PALLADIUM; HYDRODEFLUORINATION; SOLVENTS; DEHALOGENATION; CARBONYLATION; CHLORIDES;

D O I：

10.1007/s11172-013-0005-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel complex-catalyzed hydrodefluorination of acet(pentafluoroanilide) with zinc in ionic liquids resulted in the corresponding 2,3,4,5-tetrafluoro, 3,4,5-trifluoro, and 3,4-difluoro derivatives. The influence of the ionic liquid nature and the reaction conditions on its selectivity were studied, a possibility of the multiple reuse of the ionic liquids as the reaction media was demonstrated.

引用

页码：33 / 38

页数：6

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