Activation of C-F bonds in ionic liquids catalyzed by nickel complex compounds

被引：4
|
作者：
Prikhod'ko, S. A. [1 ]
Adonin, N. Yu [1 ]
Parmon, V. N. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
metal complex catalysis; activation of C-F bond; ionic liquids; acet(pentafluoroanilide); nickel complexes; 2,2 '-bipyridine; 1,10-phenanthroline; hydrodefluorination; 3,4,5-trifluoroaniline; organofluorine compounds; CROSS-COUPLING REACTIONS; HECK REACTION; ARYL HALIDES; HIGHLY EFFICIENT; PALLADIUM; HYDRODEFLUORINATION; SOLVENTS; DEHALOGENATION; CARBONYLATION; CHLORIDES;
D O I：
10.1007/s11172-013-0005-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nickel complex-catalyzed hydrodefluorination of acet(pentafluoroanilide) with zinc in ionic liquids resulted in the corresponding 2,3,4,5-tetrafluoro, 3,4,5-trifluoro, and 3,4-difluoro derivatives. The influence of the ionic liquid nature and the reaction conditions on its selectivity were studied, a possibility of the multiple reuse of the ionic liquids as the reaction media was demonstrated.
引用
收藏
页码：33 / 38
页数：6
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