Reversible releasing of arms from star morphology polymers

被引：28
作者：
Aumsuwan, Nattharika [1 ]
Urban, Marek W. [1 ]
机构：
[1] Univ So Mississippi, Shelby Thames Polymer Sci Res Ctr, Sch Polymers & High Performance Mat, Hattiesburg, MS 39406 USA
来源：
POLYMER | 2009年 / 50卷 / 01期
基金：
美国国家科学基金会;
关键词：
Star polymers; Reversible release of arms; Diels-Alder chemistry; DIELS-ALDER REACTION; MALEIMIDE; NETWORKS; HYDROGEL;
D O I：
10.1016/j.polymer.2008.10.048
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Reversible thermally induced arm release from a star polymer morphology was prepared which consists of furanic functional core and maleimide functional arm which are attached or detached via Diels-Alder (DA) reversible reactions. This approach allows the reversible bonding and deboncling at 35-40 degrees C (DA) and 90-100 degrees C (retro-DA). The covalent reversibility of this process consists of 7 cycles of the DA and retro-DA reactions. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：33 / 36
页数：4
相关论文
共 29 条
  • [1] Synthesis of organic-inorganic polymer hybrids controlled by Diels-Alder reaction
    Adachi, K
    Achimuthu, AK
    Chujo, Y
    [J]. MACROMOLECULES, 2004, 37 (26) : 9793 - 9797
  • [2] Switchable friction of stimulus-responsive hydrogels
    Chang, Debby P.
    Dolbow, John E.
    Zauscher, Stefan
    [J]. LANGMUIR, 2007, 23 (01) : 250 - 257
  • [3] A thermally re-mendable cross-linked polymeric material
    Chen, XX
    Dam, MA
    Ono, K
    Mal, A
    Shen, HB
    Nutt, SR
    Sheran, K
    Wudl, F
    [J]. SCIENCE, 2002, 295 (5560) : 1698 - 1702
  • [4] Chen Y, 1997, J POLYM SCI POL CHEM, V35, P613
  • [5] A NOVEL NONIONIC HYDROGEL FROM 2-METHYL-2-OXAZOLINE .4. REVERSIBLE GELATION OF POLYOXAZOLINE BY MEANS OF DIELS-ALDER REACTION
    CHUJO, Y
    SADA, K
    SAEGUSA, T
    [J]. MACROMOLECULES, 1990, 23 (10) : 2636 - 2641
  • [6] A new synthetic route to authentic N-substituted aminomaleimides
    Conley, NR
    Hung, RJ
    Willson, CG
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (11) : 4553 - 4555
  • [7] endo- and exo-stereochemistry in the Diels-Alder reaction: Kinetic versus thermodynamic control
    Cooley, JH
    Williams, RV
    [J]. JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (05) : 582 - 585
  • [8] Preparation of 3-arm star polymers (A3) via Diels-Alder click reaction
    Dag, Aydan
    Durmaz, Hakan
    Hizal, Gurkan
    Tunca, Umit
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (01) : 302 - 313
  • [9] A REVIEW OF THERMALLY CONTROLLED COVALENT BOND FORMATION IN POLYMER CHEMISTRY
    ENGLE, LP
    WAGENER, KB
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-REVIEWS IN MACROMOLECULAR CHEMISTRY AND PHYSICS, 1993, C33 (03): : 239 - 257
  • [10] Dynamic covalent approach to [2]- and [3]rotaxanes by utilizing a reversible thiol-disulfide interchange reaction
    Furusho, Y
    Oku, T
    Hasegawa, T
    Tsuboi, A
    Kihara, N
    Takata, T
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (12) : 2895 - 2903
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