Hydrogenation and Gettering Compatible p-Type Contacts for Multicrystalline Silicon Cells, Free of Light, and Elevated Temperature Induced Degradation

被引:0
作者
Western, Ned J. [1 ]
Bremner, Stephen P. [1 ]
机构
[1] Univ New South Wales, Sch Photovolta & Renewable Energy Engn, Sydney, NSW 2052, Australia
来源
IEEE JOURNAL OF PHOTOVOLTAICS | 2020年 / 10卷 / 05期
关键词
Surface treatment; Dielectrics; Silicon; Degradation; Dielectric breakdown; Metals; Surface emitting lasers; Laser doping; light-and-elevated-temperature-induced degradation (LeTID); multicrystalline silicon (mc-Si); silicon solar cells; CARRIER-INDUCED DEGRADATION; DEFECT; LAYERS;
D O I
10.1109/JPHOTOV.2020.2999869
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Results for a room temperature contacting method applied to the p-type rear surface of monocrystalline and multicrystalline solar cell structures are presented. Monocrystalline silicon devices with the rear contacts prepared using the point contacting by localized dielectric breakdown method are reported with an efficiency of 19.2%. The devices show improved measurements of key performance metrics of rho(c) of 1.6 +/- 0.8 m omega cm(2) and J(0)(c) of 2100 +/- 650 fAcm(-2). This contacting approach is also demonstrated for multicrystalline silicon cells, with no evidence of parasitic breakdown at grain boundary sites. The multicrystalline device implementation highlights a key advantage of this contacting method, namely a relatively free choice of annealing temperature. This flexibility allows process optimization such that the activation of light-and-elevated-temperature-induced degradation is prevented in hydrogenated multicrystalline silicon, while still maximizing the benefits to bulk lifetime.
引用
收藏
页码:1232 / 1238
页数:7
相关论文
共 41 条
[1]   Investigation of edge recombination effects in silicon solar cell structures using photoluminescence [J].
Abbott, MD ;
Cotter, JE ;
Trupke, T ;
Bardos, RA .
APPLIED PHYSICS LETTERS, 2006, 88 (11)
[2]  
[Anonymous], 2014, P 29 EUR PHOT SOL EN, DOI DOI 10.4229/EUPVSEC20142014-2BO.3.6
[3]   Gettering of transition metal impurities during phosphorus emitter diffusion in multicrystalline silicon solar cell processing [J].
Bentzen, A. ;
Holt, A. ;
Kopecek, R. ;
Stokkan, G. ;
Christensen, J. S. ;
Svensson, B. G. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (09)
[4]  
Blum A., 2013, P 28 EUR PHOT SOL EN
[5]   Lifetime degradation and regeneration in multicrystalline silicon under illumination at elevated temperature [J].
Bredemeier, Dennis ;
Walter, Dominic ;
Herlufsen, Sandra ;
Schmidt, Jan .
AIP ADVANCES, 2016, 6 (03)
[6]   Instability of Increased Contact Resistance in Silicon Solar Cells Following Post-Firing Thermal Processes [J].
Chan, Catherine ;
Hamer, Phillip ;
Bourret-Sicotte, Gabrielle ;
Chen, Ran ;
Ciesla, Alison ;
Hallam, Brett ;
Payne, David ;
Bonilla, Ruy S. ;
Wenham, Stuart .
SOLAR RRL, 2017, 1 (11)
[7]   Rapid Stabilization of High-Performance Multicrystalline P-type Silicon PERC Cells [J].
Chan, Catherine E. ;
Payne, David N. R. ;
Hallam, Brett J. ;
Abbott, Malcolm D. ;
Fung, Tsun H. ;
Wenham, Alison M. ;
Tjahjono, Budi S. ;
Wenham, Stuart R. .
IEEE JOURNAL OF PHOTOVOLTAICS, 2016, 6 (06) :1473-1479
[8]   Evidence of an identical firing-activated carrier-induced defect in monocrystalline and multicrystalline silicon [J].
Chen, Daniel ;
Kim, Moonyong ;
Stefani, Bruno V. ;
Hallam, Brett J. ;
Abbott, Malcolm D. ;
Chan, Catherine E. ;
Chen, Ran ;
Payne, David N. R. ;
Nampalli, Nitin ;
Ciesla, Alison ;
Fung, Tsun H. ;
Kim, Kyung ;
Wenham, Stuart R. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 172 :293-300
[9]   OHMIC CONTACTS FOR GAAS DEVICES [J].
COX, RH ;
STRACK, H .
SOLID-STATE ELECTRONICS, 1967, 10 (12) :1213-+
[10]   Extracting Metal Contact Recombination Parameters From Effective Lifetime Data [J].
Dumbrell, Robert ;
Juhl, Mattias K. ;
Trupke, Thorsten ;
Hameiri, Ziv .
IEEE JOURNAL OF PHOTOVOLTAICS, 2018, 8 (06) :1413-1420