Antioxidant capacity of cocoa beans and chocolate assessed by FTIR

被引:83
|
作者
Batista, Nadia Nara [2 ]
de Andrade, Dayana Pereira [1 ]
Ramos, Cintia Lacerda [1 ]
Dias, Disney Ribeiro [2 ]
Schwan, Rosane Freitas [1 ]
机构
[1] Univ Fed Lavras, Dept Biol, Campus Univ 3037, BR-37200000 Lavras, MG, Brazil
[2] Univ Fed Lavras, Dept Food Sci, Campus Univ 3037, BR-37200000 Lavras, MG, Brazil
关键词
Antioxidant activity; Total phenolic compounds; DPPH; ABTS; PLS analysis; Chocolate; THEOBROMA-CACAO; PURINE ALKALOIDS; DARK CHOCOLATE; METHYLXANTHINES; POLYPHENOLS; CAFFEINE; (-)-EPICATECHIN; FERMENTATIONS; PROCYANIDINS; SPECTROSCOPY;
D O I
10.1016/j.foodres.2016.10.028
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The total antioxidant capacity (TAC) and total phenolic compounds (TPC) of cocoa beans and chocolate produced from spontaneous and inoculated fermentations of different cocoa varieties were evaluated. Fourier transform infrared spectroscopy (FTIR), as well as conventional methods: 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), was used to determine TAC and TPC. Chocolate showed higher (p < 0.05) TPC (47.17-57.16 mg GAE/g) and TAC (1.66-233 mM TE/g and 8.86-11.35 mM TE/g as measured by DPPH and ABTS, respectively) than cocoa beans (6.30-26.05 mg GAE/g, 0.24-1.17 mM TE/g and 1.29-4.83 mM TE/g for TPC, DPPH and ARTS, respectively). Partial least square (PLS) model for infrared data showed a good calibration coefficient (R(2)cal > 0.94), indicating that the FTIR technique represents a fast and reliable tool to evaluate TPC and TAC in cocoa beans and chocolate. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:313 / 319
页数:7
相关论文
共 50 条
  • [1] Antioxidant capacity and phenolic content of cocoa beans
    Othman, Azizah
    Ismail, Amin
    Ghani, Nawalyah Abdul
    Adenan, Ilham
    FOOD CHEMISTRY, 2007, 100 (04) : 1523 - 1530
  • [2] Yeast, cocoa beans and chocolate
    Fleet, Graham
    Dircks, Hugh
    MICROBIOLOGY AUSTRALIA, 2007, 28 (02) : 48 - 50
  • [3] Procyanidin and catechin contents and antioxidant capacity of cocoa and chocolate products
    Gu, Liwei
    House, Suzanne E.
    Wu, Xianli
    Ou, Boxin
    Prior, Ronald L.
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2006, 54 (11) : 4057 - 4061
  • [4] Phenolic content and antioxidant capacity of hybrid variety cocoa beans
    Jonfia-Essien, W. A.
    West, G.
    Alderson, P. G.
    Tucker, G.
    FOOD CHEMISTRY, 2008, 108 (03) : 1155 - 1159
  • [5] Changes of phenolic compounds and antioxidant capacity in cocoa beans processing
    Jolic, Slavica Mazor
    Redovnikovic, Ivana Radojcic
    Markovic, Ksenija
    Sipusic, Durdica Ivanec
    Delonga, Karmela
    INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2011, 46 (09): : 1793 - 1800
  • [6] CHARACTERIZATION AND QUANTIFICATION OF STARCH IN COCOA BEANS AND CHOCOLATE PRODUCTS
    SCHMIEDER, RL
    KEENEY, PG
    JOURNAL OF FOOD SCIENCE, 1980, 45 (03) : 555 - &
  • [7] Procyanidin (PC) content and total antioxidant capacity (TAC) of chocolate and cocoa products
    Gu, LW
    Wu, XL
    Ou, BX
    Harnly, J
    Prior, RL
    FASEB JOURNAL, 2005, 19 (05): : A1032 - A1032
  • [8] Epicatechin content and antioxidant capacity of cocoa beans from four different countries
    Othman, Azizah
    Jalil, Abbe Maleyki Mhd
    Weng, Kong Kin
    Ismail, Amin
    Abd Ghani, Nawalyah
    Adenan, Ilham
    AFRICAN JOURNAL OF BIOTECHNOLOGY, 2010, 9 (07): : 1052 - 1059
  • [9] HPLC method for the quantification of procyanidins in cocoa and chocolate samples and correlation to total antioxidant capacity
    Adamson, GE
    Lazarus, SA
    Mitchell, AE
    Prior, RL
    Cao, GH
    Jacobs, PH
    Kremers, BG
    Hammerstone, JF
    Rucker, RB
    Ritter, KA
    Schmitz, HH
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (10) : 4184 - 4188
  • [10] Improvement of the Flavanol Profile and the Antioxidant Capacity of Chocolate Using a Phenolic Rich Cocoa Powder
    Gonzalez-Barrio, Rocio
    Nunez-Gomez, Vanesa
    Cienfuegos-Jovellanos, Elena
    Garcia-Alonso, Francisco Javier
    Periago-Caston, Ma Jesus
    FOODS, 2020, 9 (02)