The influence of hierarchical zeolite composition and pore structure on behavior of cobalt-based Fischer-Tropsch synthesis catalysts

被引：10
|
作者：
Zhao, Weiming [1 ]
Wang, Yuelun [1 ]
Li, Zhuo [2 ]
Wang, Hui [2 ]
Wu, Jinhu [2 ]
Huang, Jun [1 ]
Zhao, Yunpeng [1 ]
机构：
[1] China Univ Min & Technol, Sch Chem Engn, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuel, Qingdao 266101, Peoples R China
来源：
JOURNAL OF POROUS MATERIALS | 2015年 / 22卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Hierarchical zeolites; Si/Al ratio; Cobalt catalyst; Deactivation; Fischer-Tropsch synthesis; SYNTHESIS GAS; HYDROCARBONS; RUTHENIUM; CO; DECOMPOSITION; SELECTIVITY; METHANE; SUPPORT; NI;
D O I：
10.1007/s10934-015-9984-y
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Cobalt catalyst supported on hierarchical zeolite possessing a three different Si/Al ratio was studied in Fischer-Tropsch synthesis. The catalyst with Si/Al ratio of 60 was found to be superior to other catalysts in terms of better C5-18 selectivity and higher olefin/paraffin ratio due to smaller cobalt particles and larger number of acidic sites. While Co/Meso-ZSM120 catalyst with perfect crystal structure favored products to accessibility and prevented cobalt particles from being oxidized compared to that of amorphous support, resulting in the lowest deactivation rate and the lowest carbon content on the surface.
引用
收藏
页码：1097 / 1104
页数：8
相关论文
共 50 条
  • [1] The influence of hierarchical zeolite composition and pore structure on behavior of cobalt-based Fischer–Tropsch synthesis catalysts
    Weiming Zhao
    Yuelun Wang
    Zhuo Li
    Hui Wang
    Jinhu Wu
    Jun Huang
    Yunpeng Zhao
    Journal of Porous Materials, 2015, 22 : 1097 - 1104
  • [2] The Influence of Alkali Treatment for Synthesizing Hierarchical Zeolite on Behavior of Cobalt Fischer-Tropsch Synthesis Catalysts
    Wang, Yuelun
    Cao, Xuewen
    Jiang, Yuan
    Zhang, Hong
    Liang, Jing
    Wang, Hui
    Li, Zhuo
    Wu, Jinhu
    CATALYSIS SURVEYS FROM ASIA, 2017, 21 (01) : 28 - 36
  • [3] Deactivation of Cobalt-Based Catalysts for Fischer-Tropsch Synthesis
    Shi Lihong
    Li Xiaofeng
    Li Debao
    Sun Yuhan
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (12) : 1483 - 1488
  • [4] The Development of Cobalt-Based Catalysts for Fischer-Tropsch Synthesis
    Sun Yuhan
    Chen Jiangang
    Wang Jungang
    Jia Litao
    Hou Bo
    Li Debao
    Zhang Juan
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (08) : 919 - 927
  • [5] Progress in cobalt-based catalysts in Fischer-Tropsch synthesis of hydrocarbons
    Yin, DH
    Li, WH
    Yang, WS
    Zhong, B
    Peng, SY
    PROGRESS IN CHEMISTRY, 2001, 13 (02) : 118 - 127
  • [6] Recent advances in cobalt-based Fischer-Tropsch synthesis catalysts
    Suo, Yujun
    Yao, Yali
    Zhang, Yusheng
    Xing, Sijia
    Yuan, Zhong-Yong
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2022, 115 : 92 - 119
  • [7] Study on the Deactivation of Cobalt-based Fischer-Tropsch Synthesis Catalysts
    Hora, Lukas
    Rubas, Vlastimil
    Martinez, Augustin
    PROCEEDINGS OF THE 1ST INTERNATIONAL CONFERENCE ON CHEMICAL TECHNOLOGY, 2013, : 72 - 77
  • [8] Recent advances in cobalt-based catalysts for Fischer-Tropsch synthesis
    Hao, Qingqing
    Song, Yonghong
    Zhao, Yonghua
    Zhang, Qijian
    Liu, Zhaotie
    Liu, Zhongwen
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2019, 38 (01): : 291 - 303
  • [9] Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts
    Iglesia, E
    APPLIED CATALYSIS A-GENERAL, 1997, 161 (1-2) : 59 - 78
  • [10] Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts
    Department of Chemical Engineering, University of California, Berkeley, CA 94720, United States
    Appl Catal A Gen, 1-2 (59-78):
12345