Reactions of chlorotitanium tri-iso-propoxide with methanol and tributylamine

被引:2
作者
Fric, Helmut [1 ]
Schubert, Ulrich [1 ]
机构
[1] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria
基金
奥地利科学基金会;
关键词
titanium alkoxide derivatives; chloro alkoxo compounds; X-ray structure analyses;
D O I
10.1007/s10971-008-1706-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Reactions of TiCl((OPr)-Pr-i)(3) with methanol or tributylamine in heptane resulted in the formation of crystalline Ti4Cl2(mu(3)-OMe)(2)(mu(2)-OMe)(4)((OPr)-Pr-i)(8) and [Bu3NH][Ti2Cl3((OPr)-Pr-i)(6)], respectively. The solid state structures of both compounds are described.
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页码:2 / 5
页数:4
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