Rh(III)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C-H activation

被引：97

作者：

Shi, Zhuangzhi ^{[1
]}

Boultadakis-Arapinis, Melissa ^{[1
]}

Koester, Dennis C. ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 20期

基金：

欧洲研究理事会;

关键词：

AROMATIC IMINES; EFFICIENT SYNTHESIS; BOND ACTIVATION; ANNULATION; INDOLIZIDINE; HYDROARYLATION; AGONIST; ALKYNES; ACID;

D O I：

10.1039/c4cc00029c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biologically interesting fused oligocyclic lactams have been prepared via an intramolecular redox-neutral cyclization process. By the proper choice of the substrates with a wide variety of tethered olefins, the less favored C-H bond can be activated and functionalized. This C-H activation proceeds under mild conditions, obviates the need for external oxidants, and displays a broad scope with respect to the substituents.

引用

页码：2650 / 2652

页数：3

共 50 条

[21] Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation
Wang, Qiang
Xie, Fang
Li, Xingwei
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (16) : 8361 - 8366
[22] Rhodium-Catalyzed Redox-Neutral Olefination of Aryldiazenes with Acrylate Esters via C-H Activation and Transfer Hydrogenation
Zhang, Xiaofei
Zhang, Bin
Li, Xingwei
ORGANIC LETTERS, 2021, 23 (05) : 1687 - 1691
[23] Rh(III)-catalyzed C-H activation/cyclization of benzamides and diazo compounds to form isocoumarins and α-pyrones
Li, Xing Guang
Sun, Min
Liu, Kai
Jin, Qiao
Liu, Pei Nian
CHEMICAL COMMUNICATIONS, 2015, 51 (12) : 2380 - 2383
[24] Harnessing Vinyl Acetate as an Acetylene Equivalent in Redox-Neutral Cp*Co(III)-Catalyzed C-H Activation/Annulation for the Synthesis of Isoquinolones and Pyridones
Rana, Tamanna
Ghosh, Arijit
Aher, Yogesh N. N.
Pawar, Amit B. B.
ACS OMEGA, 2023, 8 (28): : 25262 - 25271
[25] Ruthenium-Catalyzed Redox-Neutral C-H Activation via N-N Cleavage: Synthesis of N-Substituted Indoles
Zhang, Zhenxing
Jiang, Hao
Huang, Yong
ORGANIC LETTERS, 2014, 16 (22) : 5976 - 5979
[26] Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C-H Alkenylation/Annulation Sequence
Ikemoto, Hideya
Yoshino, Tatsuhiko
Sakata, Ken
Matsunaga, Shigeki
Kanai, Motomu
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (14) : 5424 - 5431
[27] The regioselective synthesis of 2-phosphinoylindoles via Rh(III)-catalyzed C-H activation
Wang, Huanan
Li, Shuaiqi
Wang, Baiquan
Li, Bin
ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (01): : 88 - 91
[28] α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed C-H Activation for the Synthesis of N-Heterocycles
Yu, Da-Gang
de Azambuja, Francisco
Glorius, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (10) : 2754 - 2758
[29] Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed C-H Activation: Redox-Neutral and Traceless by N-N Bond Cleavage
Zhao, Dongbing
Shi, Zhuangzhi
Glorius, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (47) : 12426 - 12429
[30] Rhodium(III)-Catalyzed C-H Activation of Benzoylacetonitriles and Cyclization with Sulfoxonium Ylides to Naphthols
Zhou, Chaofan
Fang, Feifei
Cheng, Yilang
Li, Yazhou
Liu, Hong
Zhou, Yu
ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (13) : 2546 - 2551

← 1 2 3 4 5 →