Synthesis of optically active propargylic alcohols

被引：0

作者：

He, QW ^{[1
]}

Ma, SM ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 22卷 / 06期

关键词：

optically active propargylic alcohol; asymmetric reduction; asymmetric 1,2-addition; kinetic resolution; 2,3 sigma-rearrangement; elimination; reductive cleavage;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active. propargylic alcohols are important building blocks for the synthesis of various kinds of compounds with potentials and there are many methods to synthesize them. Usually, they can be prepared by asymmetric reduction, asymmetric 1,2-addition, kinetic resolution, 2,3 sigma-rearrangement, elimination or reductive cleavage of optically active acetylenic acetals. The ee values and chemical yields are good.

引用

页码：375 / 387

页数：13

共 45 条

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