Syntheses, structures, and magnetic properties of five coordination polymers constructed from biphenyl-3,4′,5-tricarboxylic acid and (bis)imidazole linkers

被引:50
作者
Zhang, Xiutang [1 ,2 ]
Fan, Liming [1 ,2 ]
Zhang, Wei [1 ]
Fan, Weiliu [2 ]
Sun, Liming [2 ]
Zhao, Xian [2 ]
机构
[1] Qilu Normal Univ, Coll Chem & Chem Engn, Adv Mat Inst Res, Jinan 250013, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; PHYSICAL-PROPERTIES; LIGAND SYNTHESES; BIS-IMIDAZOLE; SERIES; LUMINESCENCE; NETWORKS; 2D; TEMPERATURE;
D O I
10.1039/c3ce42565g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Five coordination polymers (CPs), namely {[Ni-1.5(BPT)(1,4-bib)(2)(H2O)]center dot(1,4-bib)(0.5)center dot 2H(2)O}(n) (1), {[Co-2(BPT)(1,3-bimb)(mu(3)-OH)]center dot H2O}(n) (2), {[Zn(HBPT)(1,3-bimb)]center dot H2O}(n) (3), {[Co-2(BPT)(H2BPT)(4,4'-bibp)(2)]center dot 2H(2)O}(n) (4), and [Mn-2.5(BPT)(4,4'-bibp)(2.5)(SO4)(H2O)](n) (5) (H3BPT = biphenyl-3,4',5-tricarboxylic acid, 1,4-bib = 1,4-bis(1H-imidazol-1-yl)benzene, 1,3-bimb = 1,3-bis(imidazol-1-ylmethyl)benzene, and 4,4'-bibp = 4,4'-bis(imidazol-1-yl)biphenyl), were synthesized under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. Complex 1 exhibits unprecedented 2D + 2D -> 3D parallel entangled networks consisting of trilayer (3,4,6)-connected (4(4).5(4).6(6).8)(5.6(4).8)(2)(5(2).6(2)) sheets. Complex 2 displays a 3D (3,10)-connected 3,10T9 net based on tetranuclear {Co-4(mu(3)-OH)(2)} clusters with the Schlafli symbol (4(18).6(24).8(3))(4(3))(2). Complex 3 shows an interesting 1D tube-like chain consisting of Zn-2(1,3-bimb)(2) loops. Complex 4 affords a 2D (4(4).6(2))-sql net constructed from {Co-2} dinuclear units. Complex 5 displays a 3D 6-connected (4(12).6(3))-pcu net consisting of alpha-Po primitive cubic nets based on {Mn-5(SO4)(2)} clusters. Moreover, magnetic studies indicate that complexes 2, 4 and 5 show antiferromagnetic properties.
引用
收藏
页码:3203 / 3213
页数:11
相关论文
共 57 条
[1]   Syntheses, Crystal Structures, and Magnetic Properties of Metal-Organic Hybrid Materials of Co(II) Using Flexible and Rigid Nitrogen-Based Ditopic Ligands as Spacers [J].
Ahmad, Musheer ;
Sharma, Mamsh K. ;
Das, Raja ;
Poddar, Pankai ;
Bharadwaj, Parimal K. .
CRYSTAL GROWTH & DESIGN, 2012, 12 (03) :1571-1578
[2]   Solvent-Driven Structural Diversities in ZnII Coordination Polymers and Complexes Derived from Bis-pyridyl Ligands Equipped with a Hydrogen-Bond-Capable Urea Backbone [J].
Banerjee, Subhabrata ;
Adarsh, N. N. ;
Dastidar, Parthasarathi .
CRYSTAL GROWTH & DESIGN, 2012, 12 (12) :6061-6067
[3]   Vertex-, face-, point-, Schlafli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology [J].
Blatov, V. A. ;
O'Keeffe, M. ;
Proserpio, D. M. .
CRYSTENGCOMM, 2010, 12 (01) :44-48
[4]   TOPOS3.2:: A new version of the program package for multipurpose crystal-chemical analysis [J].
Blatov, VA ;
Shevchenko, AP ;
Serezhkin, VN .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 :1193-1193
[5]   Family of Mixed 3d-4f Dimeric 14-Metallacrown-5 Compounds: Syntheses, Structures, and Magnetic Properties [J].
Cao, Fan ;
Wang, Suna ;
Li, Dacheng ;
Zeng, Suyuan ;
Niu, Meiju ;
Song, You ;
Dou, Jianmin .
INORGANIC CHEMISTRY, 2013, 52 (19) :10747-10755
[6]   High H2 adsorption in a microporous metal-organic framework with open metal sites [J].
Chen, BL ;
Ockwig, NW ;
Millward, AR ;
Contreras, DS ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749
[7]   Encapsulation of Ln3+ hydrate species for tunable luminescent materials based on a porous Cd(II)-MOF [J].
Chen, Cheng-Xia ;
Liu, Qi-Kui ;
Ma, Jian-Ping ;
Dong, Yu-Bin .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) :9027-9033
[8]   Highly-connected, porous coordination polymers based on [M4(μ3-OH)2] (M = CoII and NiII) clusters: different networks, adsorption and magnetic properties [J].
Chen, Qing ;
Xue, Wei ;
Lin, Jian-Bin ;
Lin, Rui-Biao ;
Zeng, Ming-Hua ;
Chen, Xiao-Ming .
DALTON TRANSACTIONS, 2012, 41 (14) :4199-4206
[9]   Luminescent Functional Metal-Organic Frameworks [J].
Cui, Yuanjing ;
Yue, Yanfeng ;
Qian, Guodong ;
Chen, Banglin .
CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162
[10]   Cyclometalated metal-organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines [J].
Dau, Phuong V. ;
Cohen, Seth M. .
CHEMICAL COMMUNICATIONS, 2013, 49 (55) :6128-6130