Synthesis, structure and properties of [(ZnTPP)2(μ2-4,4′-bipyridine)] (H2TPP=5,10,15,20-tetraphenyl-21H, 23H-porphyrin; 4,4′-bipy=4,4′-bipyridine)

被引：3

作者：

Chen, Wen-Tong ^{[1
,2
]}

Yao, Zhong-Liang ^{[3
]}

Wen, Ji-Wu ^{[1
]}

Yi, Xiu-Guang ^{[1
]}

Luo, Zhi-Gang ^{[1
]}

机构：

[1] Jinggangshan Univ, Inst Appl Chem, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China

[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

[3] Fujian Normal Univ, Fuqing Branch, Biol & Chem Engn Dept, Fuqing 350300, Fujian, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2013年 / 08期

关键词：

zinc; metalloporphyrin; crystal structure; fluorescence; cyclic voltammetry; solvothermal reaction; ORGANIC MATERIALS; CELLS;

D O I：

10.3184/174751913X13736450723137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metalloporphyrin [(ZnTPP)(2)(mu(2)-4,4'-bipy)], (H2TPP = 5,10,15,20-tetraphenyl-21H, 23H-porphyrin; 4,4'-bipy = 4,4'-bipyridine), has been synthesised via a solvothermal reaction and structurally characterised by single-crystal X-ray diffraction. It features a planar porphyrin macrocycle and an embedded Zn-II ion coordinating to four pyrrole nitrogen atoms and one 4,4'-bipy nitrogen atom. A photoluminescent and theoretical study shows that the complex exhibits an emission in the red region, attributed to ligand to ligand charge-transfer.

引用

页码：491 / 493

页数：3

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