Reactions of hydroxymesitylboranes with metal alkyls: An approach to new sterically hindered (metaloxy)mesitylboranes

被引：16

作者：

Anulewicz-Ostrowska, R

Lulinski, S

Pindelska, E

Serwatowski, J

机构：

[1] Warsaw Univ, Fac Chem, PL-02093 Warsaw, Poland

[2] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 09期

关键词：

D O I：

10.1021/ic0112490

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of mesitylboronic acid with alkyl derivatives of aluminum R3Al (R = Me, Et, Bu-i), gallium (Me3Ga), and zinc (Et2Zn) were investigated. The treatment of mesitylboronic acid, MesB(OH)(2), with trimethylgallium afforded the discrete dimer [mu-(MesB(OH)O)GaMe2](2) (1), which is the simple example of a O-metalated boronic acid with no hydrogen bonding in the crystal lattice. In addition, the reaction of dimesitylborinic acid, Mes(2)BOH, with diethylzinc produced the low-valent zinc compound [(mu-Mes(2)BO)ZnEt](2) (2), which was also characterized by X-ray diffraction.

引用

页码：2525 / 2528

页数：4

共 19 条

[1] Diverse reactivity of dialkylaluminum dimesitylboryloxides [(μ-Mes2BO)AlR2]2.: Synthetic and structural study
Anulewicz-Ostrowska, R
Lulinski, S
Serwatowski, J
Suwinska, K
[J]. INORGANIC CHEMISTRY, 2000, 39 (25) : 5763 - 5767
[2] Synthesis and characterization of dialkylmetal boryloxides [(μ-9-BBN-9-O)MMe2]2, M = Al, Ga, In
Anulewicz-Ostrowska, R
Lulinski, S
Serwatowski, J
[J]. INORGANIC CHEMISTRY, 1999, 38 (17) : 3796 - 3800
[3] LIPOPHILIC LITHIUM ALKOXIDES OR DIALKYLBOROXIDES - X-RAY STRUCTURES OF [LI(MU-OR')]2 AND LI(OBR2)(TMEDA), [TMEDA = (ME2NCH2)2, R = CH(SIME3)2, R' = CBUT3 OR BR2]
BECK, G
HITCHCOCK, PB
LAPPERT, MF
MACKINNON, IA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (18) : 1312 - 1314
[4] STUDIES IN STEREOCHEMISTRY .22. THE PREPARATION AND REACTIONS OF TRIMESITYLBORANE - EVIDENCE FOR THE NON-LOCALIZED NATURE OF THE ODD ELECTRON IN TRIARYLBORANE RADICAL IONS AND RELATED FREE RADICALS
BROWN, HC
DODSON, VH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (09) : 2302 - 2306
[5] DIMESITYLBORYL COMPOUNDS .1. ALKYL DERIVATIVES
BROWN, NMD
DAVIDSON, F
WILSON, JW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 185 (02) : 277 - 282
[6] STERICALLY HINDERED ORGANOTIN COMPOUNDS .3. THE REACTION BETWEEN DI-TERT-BUTYLTIN OXIDE AND ORGANOBORONIC ACIDS
BROWN, P
MAHON, MF
MOLLOY, KC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24): : 3503 - 3509
[7] BURNETT MN, 1996, 6895 ORNL
[8] SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL CHARACTERIZATION OF THE 1ST HOMOLEPTIC TRANSITION-METAL BORYLOXIDES [MN(OBTRIP2)(MU-OBTRIP2)]2 AND [FE(OBMES2)(MU-OBMES2)]2
CHEN, H
POWER, PP
SHONER, SC
[J]. INORGANIC CHEMISTRY, 1991, 30 (14) : 2884 - 2888
[9] Formation and unexpected catalytic reactivity of organoaluminum boryloxides
Gibson, VC
Mastroianni, S
White, AJP
Williams, DJ
[J]. INORGANIC CHEMISTRY, 2001, 40 (05) : 826 - +
[10] New tetrameric alkylmetal boryloxides [(μ3-R2BO)MR′]4 of zinc and cadmium with heterocubane structure
Lulinski, S
Madura, I
Serwatowski, J
Zachara, J
[J]. INORGANIC CHEMISTRY, 1999, 38 (22) : 4937 - 4941

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