Amino-catalyzed fragmentation characteristics of polyamides containing N-methylpyrrole and N-methylimidazole by electrospray negative ionization mass spectrometry

被引：1

作者：

Niu, MY

Cao, SX

Ye, Y

Zhang, Z

Zhao, YF ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem biol, Beijing 100084, Peoples R China

[2] Zhengzhou Univ, Key Lab Chem Biol, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 2006年 / 20卷 / 07期

关键词：

D O I：

10.1002/rcm.2417

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Different negative fragmentations of synthesized polyamides containing N-methylpyrrole and N-methylimidazole were analyzed by electrospray ionization tandem mass spectrometry with low-energy collision-induced dissociation. An interesting rearrangement derived from amino catalysis of N-methylimidazole was observed. The observation is useful for the study of the correlations between the sequences of polyamides and their mass fragmentation pathways. Copyright (c) 2006 John Wiley & Sons, Ltd.

引用

页码：1077 / 1081

页数：5

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