Fascinating chemistry or frustrating unpredictability: observations in crystal engineering of metal-organic frameworks

被引：97

作者：

Goesten, Maarten G. ^{[1
]}

Kapteijn, Freek ^{[1
]}

Gascon, Jorge ^{[1
]}

机构：

[1] Delft Univ Technol, Catalysis Engn Chem Engn Dept, NL-2628 BL Delft, Netherlands

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

关键词：

X-RAY-SCATTERING; COORDINATION POLYMERS; STRUCTURE-DIRECTION; ANION-EXCHANGE; SMALL-ANGLE; PORE-SIZE; DESIGN; CRYSTALLIZATION; SEPARATION; BINDING;

D O I：

10.1039/c3ce41241e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reticular design is a highly attractive concept, but coordination chemistry around the tectonic units of metal-organic frameworks (MOFs) and additional interplay with anionic and solvent species provide for dazzling complexity that effectively rules out structure prediction. We can however study the chemistry around pre-existing clusters, and assemble novel materials correspondingly, using a priori information about the connectivity of an investigated metal cluster. Studies, often spectroscopic of nature, have in recent years solved many puzzles in MOF crystallization. The obtained knowledge opens new doors in crystal engineering, but more research on MOF coordination chemistry has to be carried out.

引用

页码：9249 / 9257

页数：9

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