Room temperature switching of a neutral molecular iron(II) complex

被引：58

作者：

Schaefer, Bernhard ^{[1
]}

Rajnak, Cyril ^{[1
]}

Salitros, Ivan ^{[1
,2
]}

Fuhr, Olaf ^{[1
]}

Klar, David ^{[3
,4
]}

Schmitz-Antoniak, Carolin ^{[3
,4
]}

Weschke, Eugen ^{[5
]}

Wende, Heiko ^{[3
,4
]}

Ruben, Mario ^{[1
,6
]}

机构：

[1] Karlsruhe Inst Technol KIT, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[2] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Inst Inorgan Chem Technol & Mat, Bratislava 81237, Slovakia

[3] Univ Duisburg Essen, Fac Phys, D-47048 Duisburg, Germany

[4] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, D-47048 Duisburg, Germany

[5] Helmholtz Zentrum Berlin Mat & Energie HZB, D-12489 Berlin, Germany

[6] Univ Strasbourg, CNRS, Inst Phys & Chim Mat Strasbourg IPCMS, F-67034 Strasbourg 2, France

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 93期

关键词：

INDUCED SPIN-CROSSOVER; MAGNETIC-SUSCEPTIBILITY; STATE; LIGHT; FIELD; SPECTROSCOPY; PRESSURE; VACUUM;

D O I：

10.1039/c3cc46624h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Abrupt room temperature switching (T-c = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl) pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.

引用

页码：10986 / 10988

页数：3

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