Room temperature switching of a neutral molecular iron(II) complex

被引：58
作者：
Schaefer, Bernhard [1 ]
Rajnak, Cyril [1 ]
Salitros, Ivan [1 ,2 ]
Fuhr, Olaf [1 ]
Klar, David [3 ,4 ]
Schmitz-Antoniak, Carolin [3 ,4 ]
Weschke, Eugen [5 ]
Wende, Heiko [3 ,4 ]
Ruben, Mario [1 ,6 ]
机构：
[1] Karlsruhe Inst Technol KIT, Inst Nanotechnol, D-76021 Karlsruhe, Germany
[2] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Inst Inorgan Chem Technol & Mat, Bratislava 81237, Slovakia
[3] Univ Duisburg Essen, Fac Phys, D-47048 Duisburg, Germany
[4] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, D-47048 Duisburg, Germany
[5] Helmholtz Zentrum Berlin Mat & Energie HZB, D-12489 Berlin, Germany
[6] Univ Strasbourg, CNRS, Inst Phys & Chim Mat Strasbourg IPCMS, F-67034 Strasbourg 2, France
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 93期
关键词：
INDUCED SPIN-CROSSOVER; MAGNETIC-SUSCEPTIBILITY; STATE; LIGHT; FIELD; SPECTROSCOPY; PRESSURE; VACUUM;
D O I：
10.1039/c3cc46624h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Abrupt room temperature switching (T-c = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl) pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.
引用
收藏
页码：10986 / 10988
页数：3
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