Probing interactions by means of pulsed field gradient nuclear magnetic resonance spectroscopy

被引：10

作者：

Cozzolino, Sara ^{[1
]}

Sanna, Maria G. ^{[1
]}

Valentini, Massimiliano ^{[1
]}

机构：

[1] Instrumental Ctr Tor Mancina, Res Ctr Plant Soil Syst, Agr Res Council, I-00015 Monterotondo, Italy

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2008年 / 46卷 / S16-S23期

关键词：

PFG-NMR; H-1; diffusion coefficient; interactions; colloidal aggregates; H-bonding;

D O I：

10.1002/mrc.2345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science. Copyright (C) 2008 John Wiley & Sons, Ltd.

引用

页码：S16 / S23

页数：8

共 79 条

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