Synthesis and characterization of tantalum silsesquioxane complexes

被引：9
|
作者：
Guillo, Pascal [1 ,2 ]
Fasulo, Meg E. [1 ]
Lipschutz, Michael I. [1 ]
Tilley, T. Don [1 ,2 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 06期
关键词：
CARBON-MONOXIDE CLEAVAGE; HIGHLY-ACTIVE CATALYSTS; EPOXIDATION CATALYSTS; SILICA; METATHESIS; CHEMISTRY; ALKANES; MODELS; SITES; SILOX;
D O I：
10.1039/c2dt32601a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tantalum polyhedral oligosilsesquioxane (POSS) complexes have been synthesised and characterized. X-ray structures of these complexes revealed that the coordination number of the tantalum center greatly affects the cube-like silsesquioxane framework.
引用
收藏
页码：1991 / 1995
页数：5
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