Synthesis and characterization of luminescent room temperature ionic liquids based on Ru(bpy)(CN)42-

被引：20

作者：

Gago, Sandra ^{[1
]}

Cabrita, Luis ^{[1
]}

Carlos Lima, J. ^{[1
]}

Branco, Luis C. ^{[1
]}

Pina, Fernando ^{[1
]}

机构：

[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE, P-2829516 Monte De Caparica, Portugal

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 17期

关键词：

PHOTOPHYSICAL PROPERTIES; COORDINATION-COMPOUNDS; SOLVENTS; ADDUCTS;

D O I：

10.1039/c2dt32218h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel ammonium and phosphonium room temperature ionic liquids based on Ru(bpy)(CN)(4) as a luminescent complex anion have been developed and characterized by comparative absorption, emission, NMR and electrochemical studies as well as the evaluation of their polarity behaviour.

引用

页码：6213 / 6218

页数：6

共 33 条

[11] Halogen Bonded Supramolecular Assemblies of [Ru(bipy)(CN)4]2- Anions and N-Methyl-Halopyridinium Cations in the Solid State and in Solution [J].

Derossi, Sofia ;

Brammer, Lee ;

Hunter, Christopher A. ;

Ward, Michael D. .

INORGANIC CHEMISTRY, 2009, 48 (04) :1666-1677

[12] Synthesis and spectroscopic investigations of a crystalline humidity sensor:: Bis(triphenylphosphine) iminium 2,2′-bipyridyltetracyanoruthenate [J].

Evju, JK ;

Mann, KR .

CHEMISTRY OF MATERIALS, 1999, 11 (06) :1425-1433

[13] Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 [J].

Hallett, Jason P. ;

Welton, Tom .

CHEMICAL REVIEWS, 2011, 111 (05) :3508-3576

[14] Discovery of a magnetic ionic liquid [bmim]FeCl4 [J].

Hayashi, S ;

Hamaguchi, HO .

CHEMISTRY LETTERS, 2004, 33 (12) :1590-1591

[15] Solvatochromic parameters for solvents of interest in green chemistry [J].

Jessop, Philip G. ;

Jessop, David A. ;

Fu, Dongbao ;

Lam Phan .

GREEN CHEMISTRY, 2012, 14 (05) :1245-1259

[16]

Jiwan JLH, 1995, RECL TRAV CHIM PAY B, V114, P542

[17] Sensitization of Nanocrystalline TiO2 Anchored with Pendant Catechol Functionality Using a New Tetracyanato Ruthenium(II) Polypyridyl Complex [J].

Kar, Prasenjit ;

Verma, Sandeep ;

Sen, Anik ;

Das, Amitava ;

Ganguly, Bishwajit ;

Ghosh, Hirendra Nath .

INORGANIC CHEMISTRY, 2010, 49 (09) :4167-4174

[18] Structural and photophysical properties of adducts of [Ru(bipy)(CN)4]2- with different metal cations:: Metallochromism and its use in switching photoinduced energy transfer [J].

Lazarides, Theodore ;

Easun, Timothy L. ;

Veyne-Marti, Claire ;

Alsindi, Wassim Z. ;

George, Michael W. ;

Deppermann, Nina ;

Hunter, Christopher A. ;

Adams, Harry ;

Ward, Michael D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (13) :4014-4027

[19] An artificial antenna complex containing four Ru(bpy)32+-type chromophores as light-harvesting components and a Ru(bpy)(CN)42- subunit as the energy trap.: A structural motif which resembles the natural photosynthetic systems [J].

Loiseau, F ;

Marzanni, G ;

Quici, S ;

Indelli, MT ;

Campagna, S .

CHEMICAL COMMUNICATIONS, 2003, (02) :286-287

[20]

LYTLE FE, 1971, ANAL CHIM ACTA, V57, P239

← 1 2 3 4 →