Synthesis and characterization of luminescent room temperature ionic liquids based on Ru(bpy)(CN)42-

被引:20
作者
Gago, Sandra [1 ]
Cabrita, Luis [1 ]
Carlos Lima, J. [1 ]
Branco, Luis C. [1 ]
Pina, Fernando [1 ]
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE, P-2829516 Monte De Caparica, Portugal
关键词
PHOTOPHYSICAL PROPERTIES; COORDINATION-COMPOUNDS; SOLVENTS; ADDUCTS;
D O I
10.1039/c2dt32218h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Novel ammonium and phosphonium room temperature ionic liquids based on Ru(bpy)(CN)(4) as a luminescent complex anion have been developed and characterized by comparative absorption, emission, NMR and electrochemical studies as well as the evaluation of their polarity behaviour.
引用
收藏
页码:6213 / 6218
页数:6
相关论文
共 33 条
[1]   New members of the Ru(diimine)(CN)42- family: Structural, electrochemical and photophysical properties [J].
Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, United Kingdom ;
不详 ;
不详 .
Dalton Trans., 2006, 1 (39-50)
[2]   Solvatochromic dye sensitized nanocrystalline solar cells [J].
Argazzi, R ;
Bignozzi, CA ;
Yang, M ;
Hasselmann, GM ;
Meyer, GJ .
NANO LETTERS, 2002, 2 (06) :625-628
[3]   A SIMPLE POLY(PYRIDINE)RUTHENIUM(II) PHOTOSENSITIZER - (2,2'-BIPYRIDINE)TETRACYANORUTHENATE(II) [J].
BIGNOZZI, CA ;
CHIORBOLI, C ;
INDELLI, MT ;
SCANDOLA, MAR ;
VARANI, G ;
SCANDOLA, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7872-7873
[4]   Photophysics of supercomplexes.: A laser-induced optoacoustic study of the adducts between Ru(bpy)(CN)42- and polyaza macrocycles [J].
Borsarelli, CD ;
Braslavsky, SE ;
Indelli, MT ;
Scandola, F .
CHEMICAL PHYSICS LETTERS, 2000, 317 (1-2) :53-58
[5]   Electrochromic and magnetic ionic liquids [J].
Branco, Aida ;
Branco, Luis C. ;
Pina, Fernando .
CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2300-2302
[6]  
Branco LC, 2002, CHEM-EUR J, V8, P3671, DOI 10.1002/1521-3765(20020816)8:16<3671::AID-CHEM3671>3.0.CO
[7]  
2-9
[8]   Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality [J].
Branco, Luis C. ;
Gois, Pedro M. P. ;
Lourenco, Nuno M. T. ;
Kurteva, Vanya B. ;
Afonso, Carlos A. M. .
CHEMICAL COMMUNICATIONS, 2006, (22) :2371-2372
[9]   Chiral Guanidinium Ionic Liquids for Asymmetric Dihydroxylation of Olefins with Recycling of the Catalytic System by Supercritical CO2 [J].
Branco, Luis C. ;
Serbanovic, Ana ;
da Ponte, Manuel N. ;
Afonso, Carlos A. M. .
ACS CATALYSIS, 2011, 1 (10) :1408-1413
[10]   Intrinsically photochromic ionic liquids [J].
Branco, Luis C. ;
Pina, Fernando .
CHEMICAL COMMUNICATIONS, 2009, (41) :6204-6206