Removal of chloropyrifos ethyl, tetradifon and chlorothalonil pesticide residues from citrus by using ozone

被引：59

作者：

Kusvuran, Erdal ^{[1
]}

Yildirim, Deniz ^{[1
]}

Mavruk, Funda ^{[2
]}

Ceyhan, Mehmet ^{[2
]}

机构：

[1] Cukurova Univ, Fac Sci & Letters, Dept Chem, TR-01330 Adana, Turkey

[2] Tuna Agr Prod, Adana, Turkey

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2012年 / 241卷

关键词：

Citrus; Ozone; Chloropyrifos ethyl; Tetradifon; Chlorothalonil; POSTHARVEST CULINARY APPLICATIONS; PREHARVEST INTERVAL; OZONATED WATER; GASEOUS OZONE; REDUCTION; DEGRADATION; PRODUCE; GREENHOUSES; EXPOSURE; TOMATOES;

D O I：

10.1016/j.jhazmat.2012.09.043

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The removal of chloropyrifos ethyl, tetradifon and chlorothalonil pesticide residues from the lemon, orange and grapefruit matrices were achieved by ozonation. All of chlorothalonil residues adsorbed onto the orange matrix were completely removed after 5 min ozonation. The highest removal percentages of tetradifon and chloropyrifos ethyl were achieved as 98.6 and 94.2%, respectively for the lemon and grapefruit matrices. All of diffused chlorothalonil and chloropyrifos ethyl residues were completely removed from both orange and grapefruit matrices after 5 min ozonation. Increasing of applied ozone dosage was not significantly effect on the removal percentages of pesticides whereas increasing of ozonation temperature caused a negative effect on the removal percentages of pesticides. The washing of the matrices with tap water was not as effective as ozonation in the removal of residual pesticides. Our results show that ozone treatment has a great potential for removing of residual pesticides from lemon, orange and grapefruit matrices. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：287 / 300

页数：14

共 28 条

[1]

Anastassiades M, 2003, J AOAC INT, V86, P412

[2] Degradation of carbofuran by using ozone, UV radiation and advanced oxidation processes [J].

Benitez, FJ ;

Acero, JL ;

Real, FJ .

JOURNAL OF HAZARDOUS MATERIALS, 2002, 89 (01) :51-65

[3] Impact of high-dose, short periods of ozone exposure on green mold and antioxidant enzyme activity of tangerine fruit [J].

Boonkorn, P. ;

Gemma, H. ;

Sugaya, S. ;

Setha, S. ;

Uthaibutra, J. ;

Whangchai, K. .

POSTHARVEST BIOLOGY AND TECHNOLOGY, 2012, 67 :25-28

[4] Effect of household processing and unit-to-unit variability of pyrifenox, pyridaben, and tralomethrin residues in tomatoes [J].

Boulaid, M ;

Aguilera, A ;

Camacho, F ;

Soussi, M ;

Valverde, A .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2005, 53 (10) :4054-4058

[5] Reaction pathways and mechanisms of photodegradation of pesticides [J].

Burrows, HD ;

Canle, M ;

Santaballa, JA ;

Steenken, S .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2002, 67 (02) :71-108

[6] Residue contents of captan and procymidone applied on tomatoes grown in greenhouses and their reduction by duration of a pre-harvest interval and post-harvest culinary applications [J].

Cengiz, Mehmet F. ;

Certel, Muharrem ;

Karakas, Barcin ;

Gocmen, Huseyin .

FOOD CHEMISTRY, 2007, 100 (04) :1611-1619

[7] Residue contents of DDVP (Dichlorvos) and diazinon applied on cucumbers grown in greenhouses and their reduction by duration of a pre-harvest interval and post-harvest culinary applications [J].

Cengiz, MF ;

Certel, M ;

Göçmen, H .

FOOD CHEMISTRY, 2006, 98 (01) :127-135

[8] Oxidation kinetics of two pesticides in natural waters by ozonation and ozone combined with hydrogen peroxide [J].

Chelme-Ayala, Pamela ;

El-Din, Mohamed Gamal ;

Smith, Daniel W. ;

Adams, Craig D. .

WATER RESEARCH, 2011, 45 (08) :2517-2526

[9]

Graham D.M., 1997, FOOD TECHNOL-CHICAGO, V51, P72

[10] Use of ozone in the food industry [J].

Guzel-Seydim, ZB ;

Greene, AK ;

Seydim, AC .

LEBENSMITTEL-WISSENSCHAFT UND-TECHNOLOGIE-FOOD SCIENCE AND TECHNOLOGY, 2004, 37 (04) :453-460

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