Electrospun nano-scaled glass fiber reinforcement of Bis-GMA/TEGDMA dental composites

被引:48
作者
Gao, Yi [1 ]
Sagi, Sriramaraju [1 ]
Zhang, Lifeng [1 ]
Liao, Yiliang [1 ]
Cowles, David M. [1 ]
Sun, Yuyu [2 ]
Fong, Hao [1 ]
机构
[1] S Dakota Sch Mines & Technol, Dept Chem, Rapid City, SD 57701 USA
[2] Univ S Dakota, Biomed Engn Program, Sioux Falls, SD 57107 USA
关键词
nanocomposites; silicas; fibers; electrospinning; mechanical properties;
D O I
10.1002/app.28695
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The objective of this study was to investigate the electrospun nano-scaled glass fiber reinforcement of 2,2'-bis[4-(methacryloxypropoxy)-phenyl]-propane/triethylene glycol dimethacrylate (Bis-GMA/TEGDMA) dental composites. The hypothesis was that incorporation of the surface-silanized electrospun nano-scaled glass fibers into Bis-GMA/TEGDMA dental composites would result in substantial improvement on mechanical properties. To test the hypothesis, photo-cured Bis-GMA/TEGDMA dental composites filled with various mass fractions of surface-silanized electrospun nano-scaled glass fibers were systematically fabricated; and their mechanical properties were then evaluated. The results indicated that small mass fraction substitutions (1, 2.5, 5, and 73%) of conventional dental filler with the surface-silanized electrospun nano-scaled glass fibers, significantly improved the flexural strength, elastic modulus, and work of fracture values of 70%, (mass fraction) filled composites, by as Much as 44%, 29%, and 66%, respectively. The mechanical properties of the composites could be further improved by optimizing the chemical compositions and the surface treatment methods of the fibers. We envision that the electrospun nano-scaled glass fibers could be utilized to develop the next generation dental composites, which would be particularly useful for large posterior restorations. (C) 2008 Wiley Periodicals, Inc.
引用
收藏
页码:2063 / 2070
页数:8
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