Electrospun nano-scaled glass fiber reinforcement of Bis-GMA/TEGDMA dental composites

被引:47
作者
Gao, Yi [1 ]
Sagi, Sriramaraju [1 ]
Zhang, Lifeng [1 ]
Liao, Yiliang [1 ]
Cowles, David M. [1 ]
Sun, Yuyu [2 ]
Fong, Hao [1 ]
机构
[1] S Dakota Sch Mines & Technol, Dept Chem, Rapid City, SD 57701 USA
[2] Univ S Dakota, Biomed Engn Program, Sioux Falls, SD 57107 USA
关键词
nanocomposites; silicas; fibers; electrospinning; mechanical properties;
D O I
10.1002/app.28695
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The objective of this study was to investigate the electrospun nano-scaled glass fiber reinforcement of 2,2'-bis[4-(methacryloxypropoxy)-phenyl]-propane/triethylene glycol dimethacrylate (Bis-GMA/TEGDMA) dental composites. The hypothesis was that incorporation of the surface-silanized electrospun nano-scaled glass fibers into Bis-GMA/TEGDMA dental composites would result in substantial improvement on mechanical properties. To test the hypothesis, photo-cured Bis-GMA/TEGDMA dental composites filled with various mass fractions of surface-silanized electrospun nano-scaled glass fibers were systematically fabricated; and their mechanical properties were then evaluated. The results indicated that small mass fraction substitutions (1, 2.5, 5, and 73%) of conventional dental filler with the surface-silanized electrospun nano-scaled glass fibers, significantly improved the flexural strength, elastic modulus, and work of fracture values of 70%, (mass fraction) filled composites, by as Much as 44%, 29%, and 66%, respectively. The mechanical properties of the composites could be further improved by optimizing the chemical compositions and the surface treatment methods of the fibers. We envision that the electrospun nano-scaled glass fibers could be utilized to develop the next generation dental composites, which would be particularly useful for large posterior restorations. (C) 2008 Wiley Periodicals, Inc.
引用
收藏
页码:2063 / 2070
页数:8
相关论文
共 21 条
  • [1] MICROSCOPIC OBSERVATIONS OF THE WEAR OF A TOOTH RESTORATIVE COMPOSITE INVIVO
    ABELL, AK
    LEINFELDER, KF
    TURNER, DT
    [J]. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1983, 17 (03): : 501 - 507
  • [2] [Anonymous], POLYMERIC NANOSTRUCT
  • [3] ANTONUCCI JM, 1997, DESK REFERENCE FUNCT, P719
  • [4] UPDATE ON DENTAL COMPOSITE RESTORATIONS
    BAYNE, SC
    HEYMANN, HO
    SWIFT, EJ
    [J]. JOURNAL OF THE AMERICAN DENTAL ASSOCIATION, 1994, 125 (06) : 687 - 701
  • [5] Bowen R. L., 1962, U. S. Pat., Patent No. [3,066,112, 3066112]
  • [7] Silica nanofibers from electrospinning/sol-gel process
    Choi, SS
    Lee, SG
    Im, SS
    Kim, SH
    Joo, YL
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 2003, 22 (12) : 891 - 893
  • [8] THE BENEFITS AND RISKS OF DENTAL AMALGAM - CURRENT FINDINGS REVIEWED
    CORBIN, SB
    KOHN, WG
    [J]. JOURNAL OF THE AMERICAN DENTAL ASSOCIATION, 1994, 125 (04) : 381 - 388
  • [9] Polymer nanocomposites: The "nano" effect on mechanical properties
    Crosby, Alfred J.
    Lee, Jong-Young
    [J]. POLYMER REVIEWS, 2007, 47 (02) : 217 - 229
  • [10] Spinning continuous fibers for nanotechnology
    Dzenis, Y
    [J]. SCIENCE, 2004, 304 (5679) : 1917 - 1919