Low-temperature synthesis of multilayer graphene/amorphous carbon hybrid films and their potential application in solar cells

被引:51
作者
Cui, Tongxiang [2 ]
Lv, Ruitao [1 ]
Huang, Zheng-Hong [2 ]
Zhu, Hongwei [3 ,4 ]
Jia, Yi [5 ]
Chen, Shuxiao [2 ]
Wang, Kunlin [3 ]
Wu, Dehai [3 ]
Kang, Feiyu [2 ,5 ]
机构
[1] Penn State Univ, Dept Phys, University Pk, PA 16802 USA
[2] Tsinghua Univ, Dept Mat Sci & Engn, Adv Mat Lab, Beijing 100084, Peoples R China
[3] Tsinghua Univ, Minist Educ, Dept Mech Engn, Key Lab Adv Mfg Mat Proc Technol, Beijing 100084, Peoples R China
[4] Tsinghua Univ, Ctr Nano & Micro Mech, Beijing 100084, Peoples R China
[5] Tsinghua Univ, Grad Sch Shenzhen, Shenzhen 518055, Guangdong, Peoples R China
来源
NANOSCALE RESEARCH LETTERS | 2012年 / 7卷
基金
中国国家自然科学基金;
关键词
Graphene; Amorphous carbon; Temperature effect; Nickel foil; Solar cell; HNO3; treatment; CHEMICAL-VAPOR-DEPOSITION; GRAPHENE FILMS; GROWTH;
D O I
10.1186/1556-276X-7-453
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of reaction temperature on the synthesis of graphitic thin film on nickel substrate was investigated in the range of 400A degrees C to 1,000A degrees C. Amorphous carbon (a-C) film was obtained at 400A degrees C on nickel foils by chemical vapor deposition; hybrid films of multilayer graphene (MLG) and a-C were synthesized at a temperature of 600A degrees C, while MLG was obtained at temperatures in excess of 800A degrees C. Schottky-junction solar cell devices prepared using films produced at 400A degrees C, 600A degrees C, 800A degrees C, and 1,000A degrees C coupled with n-type Si demonstrate power conversion efficiencies of 0.003%, 0.256%, 0.391%, and 0.586%, respectively. A HNO3 treatment has further improved the efficiencies of the corresponding devices to 0.004%, 1.080%, 0.800%, and 0.820%, respectively. These films are promising materials for application in low-cost and simple carbon-based solar cells.
引用
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页数:7
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