Total Synthesis of Aspercyclides A and B via Intramolecular Oxidative Diaryl Ether Formation

被引：25
|
作者：
Yoshino, Tatsuya [2 ]
Sato, Itaru [1 ]
Hirama, Masahiro [2 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
[2] Tohoku Univ, Grad Sch Sci, Res & Analyt Ctr Giant Mol, Sendai, Miyagi 9808578, Japan
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 16期
关键词：
SHARPLESS EPOXIDATION; ENANTIOMERS;
D O I：
10.1021/ol3019727
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.
引用
收藏
页码：4290 / 4292
页数：3
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