The Hydrodeoxygenation of 2-Methoxyphenol over Ni/Kieselguhr Catalysts as a Model Reaction for Bio-oil Upgrading

被引：2
|
作者：
Jeon, J. -K. [2 ]
Huh, B. [3 ]
Lee, C. H. [2 ]
Suh, D. J. [4 ]
Suh, Y. -W. [5 ]
Heo, H. S. [6 ]
Park, Y. -K. [1 ,6 ]
机构：
[1] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea
[2] Kongju Natl Univ, Dept Chem Engn, Cheonan, South Korea
[3] Kongju Natl Univ, Reg Innovat Ctr New Mat Recycling, Gongju, South Korea
[4] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul, South Korea
[5] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
[6] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea
来源：
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS | 2013年 / 35卷 / 03期
基金：
新加坡国家研究基金会;
关键词：
bio-oil; hydrodeoxygenation; 2-methoxyphenol; MgO; Ni; kieselguhr; HYDROGENATION; PYROLYSIS;
D O I：
10.1080/15567036.2010.511427
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100 degrees C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3 + Urea, NaHCO3, and (NH4)2CO3 precipitants, the Na2CO3 + Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.
引用
收藏
页码：271 / 277
页数：7
相关论文
共 50 条
  • [21] Hydrodeoxygenation of 2-methoxyphenol over different Re active phases supported on SiO2 catalysts
    Leiva, K.
    Martinez, N.
    Sepulveda, C.
    Garcia, R.
    Jimenez, C. A.
    Laurenti, D.
    Vrinat, M.
    Geantet, C.
    Fierro, J. L. G.
    Ghampson, I. T.
    Escalona, N.
    APPLIED CATALYSIS A-GENERAL, 2015, 490 : 71 - 79
  • [22] Catalytic Hydrodeoxygenation of Algae Bio-oil over Bimetallic Ni-Cu/ZrO2 Catalysts
    Guo, Qingjie
    Wu, Man
    Wang, Kai
    Zhang, Liang
    Xu, Xiufeng
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2015, 54 (03) : 890 - 899
  • [23] Hydrodeoxygenation of 2-Methoxyphenol over Ru, Pd, and Mo2C Catalysts Supported on Carbon
    Liu, Shida
    Wang, Haiyan
    Smith, Kevin J.
    Kim, Chang Soo
    ENERGY & FUELS, 2017, 31 (06) : 6378 - 6388
  • [24] Hydrodeoxygenation of lignin bio-oil model compounds and surrogate mixtures over zeolite supported nickel catalysts
    Zormpa, Foteini F.
    Margellou, Antigoni G.
    Karakoulia, Stamatia A.
    Delli, Evangelia
    Triantafyllidis, Konstantinos S.
    CATALYSIS TODAY, 2024, 433
  • [25] Selective hydrodeoxygenation of bio-oil model compounds and mixtures over CuCoOx catalysts under mild conditions
    Zhang, Zuyi
    Wang, Xiaofeng
    Wang, Chenxiang
    Yan, Ziyi
    Zhuang, Guangyao
    Ma, Nan
    Li, Qingbo
    CHEMICAL ENGINEERING JOURNAL, 2024, 483
  • [26] Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading
    Cheng, Shouyun
    Wei, Lin
    Zhao, Xianhui
    Julson, James
    CATALYSTS, 2016, 6 (12):
  • [27] Influence of CeO2 Addition to Ni-Cu/HZSM-5 Catalysts on Hydrodeoxygenation of Bio-Oil
    Wang, Wenhe
    Zhang, Changsen
    Chen, Guanghui
    Zhang, Ruiqin
    APPLIED SCIENCES-BASEL, 2019, 9 (06):
  • [28] Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts: Effect of metal and support properties
    Sankaranarayanan, Thangaraju M.
    Berenguer, Antonio
    Ochoa-Hernandez, Cristina
    Moreno, Ines
    Jana, Prabhas
    Coronado, Juan M.
    Serrano, David P.
    Pizarro, Patricia
    CATALYSIS TODAY, 2015, 243 : 163 - 172
  • [29] Bio-oil upgrading over platinum catalysts using in situ generated hydrogen
    Fisk, Courtney A.
    Morgan, Tonya
    Ji, Yaying
    Crocker, Mark
    Crofcheck, Czarena
    Lewis, Sam A.
    APPLIED CATALYSIS A-GENERAL, 2009, 358 (02) : 150 - 156
  • [30] Hydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts
    Hita, Idoia
    Cordero-Lanzac, Tomas
    Bonura, Giuseppe
    Cannilla, Catia
    Arandes, Jose M.
    Frusteri, Francesco
    Bilbao, Javier
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2019, 80 : 392 - 400
12345