Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives

被引：36

作者：

Pan ShiGuang ^{[1
]}

Liu JinHua ^{[1
]}

Li YuanMing ^{[1
]}

Li ZhiPing ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

CHINESE SCIENCE BULLETIN | 2012年 / 57卷 / 19期

基金：

中国国家自然科学基金;

关键词：

iron-catalyzed; benzylation; toluene derivatives; C-C bond formation; C-H BONDS; OXIDATIVE ACTIVATION; METAL; FUNCTIONALIZATION; EFFICIENT; TRANSFORMATION; ALKYLATION; AMINATION; CHEMISTRY; ARYLATION;

D O I：

10.1007/s11434-012-5223-y

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

An iron-catalyzed oxidative C-C bond formation by the reactions of simple toluene derivatives with 1,3-dicarbonyl compounds is developed. A benzylic radical addition to a benzoylmethanato iron species is proposed for the transformation.

引用

页码：2382 / 2386

页数：5

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