1,4-Bis[(2,2′:6′,2"-terpyridin-4′-yl)oxy]butane

被引:2
作者
Akerman, Matthew P. [1 ]
Grimmer, Craig D. [1 ]
Nikolayenko, Varvara I. [1 ]
Reddy, Desigan [1 ]
机构
[1] Univ KwaZulu Natal, Sch Chem, ZA-3209 Pietermaritzburg, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
LIGANDS; COMPLEXES; SPACERS;
D O I
10.1107/S1600536811050343
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C34H28N6O2, has an inversion centre located at the mid-point of the central C-C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) angstrom above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)degrees, repectively. In the crystal, weak C-H center dot center dot center dot N interactions link the molecules into infinite chains parallel to the a axis.
引用
收藏
页码:O3478 / U1714
页数:11
相关论文
共 14 条
[1]   STRUCTURAL CONSIDERATIONS OF TERDENTATE LIGANDS - CRYSTAL-STRUCTURES OF 2,2'-6',2''-TERPYRIDINE AND 2,6-BIS(PYRAZOL-1-YL)PYRIDINE [J].
BESSEL, CA ;
SEE, RF ;
JAMESON, DL ;
CHURCHILL, MR ;
TAKEUCHI, KJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (22) :3223-3228
[2]   4′-Chloro-2,2′:6′,2"-terpyridine [J].
Beves, Jonathon E. ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Neuburger, Markus ;
Schaffner, Silvia .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :O2497-O2498
[3]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[4]   Linear and macrocyclic ruthenium(II) complexes containing bis(2,2′:6′,2"-terpyridine) ligands with flexible, naphthalene-centred spacers [J].
Chow, Hoi Shan ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Neuburger, Markus ;
Schaffner, Silvia .
POLYHEDRON, 2006, 25 (08) :1831-1843
[5]   Formation of [2+2] diruthenium(II) metallomacrocycles from ligands containing 2,2′:6′,2"-terpyridine domains linked through flexible polyethyleneoxy spacers [J].
Constable, EC ;
Housecroft, CE ;
Neuburger, M ;
Schaffner, S ;
Smith, CB .
DALTON TRANSACTIONS, 2005, (13) :2259-2267
[6]   METAL-MEDIATED SYNTHESIS OF MULTIDOMAIN LIGANDS - A NEW STRATEGY FOR METALLOSUPRAMOLECULAR CHEMISTRY [J].
CONSTABLE, EC ;
THOMPSON, AMWC ;
HARVESON, P ;
MACKO, L ;
ZEHNDER, M .
CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (06) :360-367
[7]   Square-planar Pd(II), Pt(II), and Au(III) terpyridine complexes: Their syntheses, physical properties, supramolecular constructs, and biomedical activities [J].
Eryazici, Ibrahim ;
Moorefield, Charles N. ;
Newkome, George R. .
CHEMICAL REVIEWS, 2008, 108 (06) :1834-1895
[8]   Synthesis of 4′-substituted-2,2′:6′,2"-terpyridines [J].
Fallahpour, RA .
SYNTHESIS-STUTTGART, 2003, (02) :155-184
[9]  
Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]
[10]  
Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]