A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water

被引：7

作者：

Silva, Aires da Conceicao ^{[1
]}

Senra, Jaqueline Dias ^{[2
]}

Ferreira de Souza, Andrea Luzia ^{[3
]}

Brum Malta, Luiz Fernando ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, RJ, Brazil

[2] Univ Fed Rio de Janeiro, Nucleo Pesquisas Prod Nat, BR-21941614 Rio De Janeiro, RJ, Brazil

[3] Univ Fed Rio de Janeiro, Inst Quim, BR-27930560 Macae, RJ, Brazil

来源：

SCIENTIFIC WORLD JOURNAL | 2013年

关键词：

CROSS-COUPLING REACTIONS; LAYERED DOUBLE HYDROXIDES; PD NANOPARTICLES; PALLADIUM; CYCLODEXTRINS; HYDROTALCITE; SHAPE;

D O I：

10.1155/2013/456789

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+ layered double hydroxide (LDH) and N,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst.

引用

页数：8

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