A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water

被引：7
作者：
Silva, Aires da Conceicao [1 ]
Senra, Jaqueline Dias [2 ]
Ferreira de Souza, Andrea Luzia [3 ]
Brum Malta, Luiz Fernando [1 ]
机构：
[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, RJ, Brazil
[2] Univ Fed Rio de Janeiro, Nucleo Pesquisas Prod Nat, BR-21941614 Rio De Janeiro, RJ, Brazil
[3] Univ Fed Rio de Janeiro, Inst Quim, BR-27930560 Macae, RJ, Brazil
来源：
SCIENTIFIC WORLD JOURNAL | 2013年
关键词：
CROSS-COUPLING REACTIONS; LAYERED DOUBLE HYDROXIDES; PD NANOPARTICLES; PALLADIUM; CYCLODEXTRINS; HYDROTALCITE; SHAPE;
D O I：
10.1155/2013/456789
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+ layered double hydroxide (LDH) and N,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst.
引用
收藏
页数：8
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