Thin film solar cells based on the heterojunction of colloidal PbS quantum dots with CdS

被引:63
作者
Bhandari, Khagendra P. [1 ]
Roland, Paul J. [1 ]
Mahabaduge, Hasitha [1 ]
Haugen, Neale O. [1 ]
Grice, Corey R. [1 ]
Jeong, Sohee [3 ]
Dykstra, Tieneke [1 ]
Gao, Jianbo [1 ,2 ]
Ellingson, Randy J. [1 ]
机构
[1] Univ Toledo, Dept Phys & Astron, Wright Ctr Photovolta Innovat & Commercializat, Toledo, OH 43606 USA
[2] NREL, Golden, CO 80401 USA
[3] Korea Inst Machinery & Mat, Nanomech Res Div, Taejon 305343, South Korea
关键词
Quantum dot; PbS; CdS; Solar cell; Thin film; CHEMICAL-VAPOR-DEPOSITION; BATH DEPOSITION; EFFICIENCY; STABILITY; NANOCRYSTALS; AIR;
D O I
10.1016/j.solmat.2013.07.018
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Here we report on heterojunction PbS quantum dot (QD) solar cells using RF magnetron sputtered CdS as the n-type window layer. These solar cells generate large open circuit voltage compared to previously reported PbS-QD solar cells. Our investigations of this device design show an optimized CdS film thickness of 70 nm and an optimized PbS QD diameter of similar to 2.7 nm, corresponding to a bandgap energy of similar to 1.57 eV. Under simulated AM 1.5 G illumination, we attain short circuit current as high as 12 mA-cm(-2), an open circuit voltage of 0.65 V and efficiency as high as 3.3%. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:476 / 482
页数:7
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