(Anilino)anthraquinone Nickel-Catalyzed Random Copolymerization of Norbornene and Ethylene

被引：23

作者：

Cheng, Hailong ^{[1
]}

Cai, Zhengguo ^{[1
]}

机构：

[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China

来源：

CHEMCATCHEM | 2018年 / 10卷 / 03期

基金：

中国国家自然科学基金;

关键词：

alkenes; copolymerization; nickel; N; O ligands; norbornene; ANSA-FLUORENYLAMIDODIMETHYLTITANIUM COMPLEX; IN-SITU FORMATION; PALLADIUM(II) COMPLEXES; VINYL-POLYMERIZATION; VINYL/ADDITION POLYMERIZATION; OLEFIN POLYMERIZATION; LIVING POLYMERIZATION; ETHENE-NORBORNENE; HIGHER; 1-ALKENE; ALPHA-OLEFINS;

D O I：

10.1002/cctc.201701418

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel complexes bearing an (anilino)anthraquinone ligand with different electron-donating substituents were synthesized and shown to have unique properties for the random copolymerization of norbornene with ethylene. The nickel catalysts exhibited high activity (380-750 kg mol(-1) h(-1)) and thermal stability in the production of cyclic olefin copolymers (COCs). The norbornene content of the obtained COCs could be controlled over a wide range (63.7-92.2 mol%) by changing the comonomer concentration in the feed. The glass transition temperature value increased linearly from 182 to 322 degrees C as a function of the norbornene content regardless of the nickel complex used.

引用

收藏

页码：497 / 500

页数：4

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