PEM fuel-cell stack design for improved fuel utilization

被引:63
作者
Han, In-Su [1 ]
Jeong, Jeehoon [1 ]
Shin, Hyun Khil [1 ]
机构
[1] GS Caltex Corp, Res & Dev Ctr, Taejon 305380, South Korea
关键词
Fuel cell; Polymer electrolyte membrane; Fuel utilization; Dead-end operation; Stack design; HYDROGEN FUEL; FLOW-RATE; MEMBRANE; PERFORMANCE; NITROGEN; PEFC; RECIRCULATION; DEGRADATION; DURABILITY; EJECTOR;
D O I
10.1016/j.ijhydene.2013.06.136
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a new design for a polymer electrolyte membrane (PEM) fuel-cell stack that can achieve higher fuel utilization without using hydrogen recirculation devices such as hydrogen pumps or ejectors, which consume parasitic power and/or require additional control schemes. The basic concept of the proposed design is to divide the anodic cells of a stack into several blocks by inserting compartments between the cells, thereby constructing a multistage anode with a single-stage cathode in a single stack. In this design, a higher gaseous flow rate is maintained at the outlet of the anodic cells, even under dead-end conditions, and this results in a reduction of purge-gas emissions by hindering the accumulation of liquid water and nitrogen in the anodic cells. A 15 kW-class PEM fuel cell stack is designed, fabricated, and tested to investigate the effectiveness of the proposed design. The experimental results indicate that the amount of purge gas is significantly reduced, and consequently, a higher fuel utilization of more than 99.6% is achieved. Additionally, the output voltage of the stack fluctuates much less than that of conventional fuel cells owing to the multistage anode design. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:11996 / 12006
页数:11
相关论文
共 31 条
[1]   Buildup of nitrogen in direct hydrogen polymer-electrolyte fuel cell stacks [J].
Ahluwalia, R. K. ;
Wang, X. .
JOURNAL OF POWER SOURCES, 2007, 171 (01) :63-71
[2]   Modeling and control of air stream and hydrogen flow with recirculation in a PEM fuel cell system - I. Control-oriented modeling [J].
Bao, Cheng ;
Ouyang, Minggao ;
Yi, Baolian .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (13) :1879-1896
[3]   Polarization study of a PEMFC with four reference electrodes at hydrogen starvation conditions [J].
Baumgartner, W. R. ;
Parz, P. ;
Fraser, S. D. ;
Wallnoefer, E. ;
Hacker, V. .
JOURNAL OF POWER SOURCES, 2008, 182 (02) :413-421
[4]   Experimental analysis of a PEM fuel cell performance at variable load with anodic exhaust management optimization [J].
Belvedere, B. ;
Bianchi, M. ;
Borghetti, A. ;
De Pascale, A. ;
Paolone, M. ;
Vecci, R. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (01) :385-393
[5]   Design and characterization of an electronically controlled variable flow rate ejector for fuel cell applications [J].
Brunner, Douglas A. ;
Marcks, Shane ;
Bajpai, Manish ;
Prasad, Ajay K. ;
Advani, Suresh G. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (05) :4457-4466
[6]   Optimization of purge cycle for dead-ended anode fuel cell operation [J].
Chen, Jixin ;
Siegel, Jason B. ;
Stefanopoulou, Anna G. ;
Waldecker, James R. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (12) :5092-5105
[7]   Experimental study on enhancing the fuel efficiency of an anodic dead-end mode polymer electrolyte membrane fuel cell by oscillating the hydrogen [J].
Choi, Jong Won ;
Hwang, Yong-Sheen ;
Cha, Suk Won ;
Kim, Min Soo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (22) :12469-12479
[8]   PEFC Stack Operating in Anodic Dead End Mode [J].
Dumercy, L. ;
Pera, M-C ;
Glises, R. ;
Hissel, D. ;
Hamandi, S. ;
Badin, F. ;
Kauffmann, J-M .
FUEL CELLS, 2004, 4 (04) :352-357
[9]   Effect of serpentine flow-field designs on performance of PEMFC stacks for micro-CHP systems [J].
Han, In-Su ;
Lim, Jongkoo ;
Jeong, Jeehoon ;
Shin, Hyun Khil .
RENEWABLE ENERGY, 2013, 54 :180-188
[10]   Customized design for the ejector to recirculate a humidified hydrogen fuel in a submarine PEMFC [J].
Kim, Minjin ;
Sohn, Young-Jun ;
Cho, Chung-Won ;
Lee, Won-Yong ;
Kim, Chang-Soo .
JOURNAL OF POWER SOURCES, 2008, 176 (02) :529-533