Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

被引：267
|
作者：
Jones, Matthew B. [1 ]
Gaunt, Andrew J. [1 ]
机构：
[1] Los Alamos Natl Lab, Inorgan Isotope & Actinide Grp, Div Chem, Los Alamos, NM 87545 USA
来源：
CHEMICAL REVIEWS | 2013年 / 113卷 / 02期
关键词：
RAY CRYSTAL-STRUCTURES; SCHIFF-BASE COMPLEXES; CATION-CATION INTERACTIONS; N-HETEROCYCLIC CARBENE; URANYL-ION COMPLEXES; CIS-DIOXIDO URANYL; C-H ACTIVATION; MOLECULAR-STRUCTURE; URANIUM(IV) COMPLEXES; PHOSPHINE OXIDE;
D O I：
10.1021/cr300198m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A study was conducted to report the latest developments in synthesis and structural chemistry of nonaqueous actinide complexes. The term nonaqueous was defined to mean those molecules whose crystal structures did not contain water. The nonaqueous molecule was included when it was synthesized using hydrated solids as precursors, but the reaction chemistry was performed exclusively in an organic solvent. All of the actinides were found to be radioactive and synthetic scale experiments were performed with appropriate analyses of hazards and implementation of controls and safety procedures concerning actinide radioisotopes.
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页码：1137 / 1198
页数：62
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