Synthesis of biodiesel from neem oil using Mg-Al nano hydrotalcite

被引:6
作者
Manivannan, R. [1 ]
Karthikeyan, C. [1 ]
机构
[1] Govt Arts Coll Autonomous, Dept Chem, Kumbakonam 612001, Tamil Nadu, India
来源
ADVANCES IN NANOSCIENCE AND NANOTECHNOLOGY | 2013年 / 678卷
关键词
Neem Biodiesel; nano Hydrotalcite; Transesterification; ACTIVATION; CATALYSTS;
D O I
10.4028/www.scientific.net/AMR.678.268
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Methyl ester of fatty acids, derived from vegetable oils or animal fats are known as biodiesel. The most common method of biodiesel production is transesterification (alcoholysis) of oil (triglycerides) with methanol in the presence of a catalyst which gives biodiesel (fatty acid methyl esters, FAME) and glycerol (by product). In this work, an environmentally benign process for the methanolysis of neem oil to methyl esters using Mg-Al nano hydrotalcites as solid base catalysts in a heterogeneous manner was developed. The effect of the reaction temperature, reaction time, catalyst amount, and methanol /oil molar ratio on the Mg-Al nano hydrotalcite was analyzed. The nano catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). Biodiesel produced from the neem oil by using Mg-Al nano hydrotalcite catalyst was analyzed by gas chromatography.
引用
收藏
页码:268 / +
页数:2
相关论文
共 15 条
[1]   The use of Mg/Al layered double hydroxide for color removal of textile wastewater [J].
bin Hussein, MZ ;
Zainal, Z ;
Yaziz, I ;
Beng, TC .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2001, 36 (04) :565-573
[2]   PARTICLE SIZE DETERMINATION FROM X-RAY LINE BROADENING [J].
BIRKS, LS ;
FRIEDMAN, H .
JOURNAL OF APPLIED PHYSICS, 1946, 17 (08) :687-691
[3]  
Choudary BM, 2001, ANGEW CHEM INT EDIT, V40, P763, DOI 10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO
[4]  
2-T
[5]   Continuous synthesis of tin and indium oxide nanoparticles in sub- and supercritical water [J].
Fang, Zhen ;
Assaaoudi, Hassane ;
Guthrie, Roderick I. L. ;
Kozinski, Janusz A. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (08) :2367-2371
[6]   Investigation of thermal stabilization of poly(vinyl chloride) by lead stearate and its combination with synthetic hydrotalcite [J].
Kalouskova, R ;
Novotna, M ;
Vymazal, Z .
POLYMER DEGRADATION AND STABILITY, 2004, 85 (02) :903-909
[7]   Biodiesel production: a review [J].
Ma, FR ;
Hanna, MA .
BIORESOURCE TECHNOLOGY, 1999, 70 (01) :1-15
[8]   Performance and emissions of biodiesel in a boiler for residential heating [J].
Macor, A. ;
Pavanello, P. .
ENERGY, 2009, 34 (12) :2025-2032
[9]  
Narayanan S., 2003, APPL CATAL A-GEN, VA198, P13
[10]  
Panda K., 2000, J MOL CATAL A-CHEM, V151, P185