A Highly Selective Catalyst for Partial Hydrogenation of 1,3-Butadiene: MgO-Supported Rhodium Clusters Selectively Poisoned with CO

被引：32
作者：
Yardimci, Dicle [1 ]
Serna, Pedro [1 ]
Gates, B. C. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
来源：
CHEMCATCHEM | 2012年 / 4卷 / 10期
关键词：
1; 3-butadiene; catalyst selectivity; selective hydrogenation; supported rhodium clusters; supported rhodium complexes; SINGLE-CRYSTAL; CARBON-MONOXIDE; METAL-CATALYSTS; ETHYLENE; PT(111); CHEMISORPTION; HYDROCARBONS; PALLADIUM; 1-BUTENE; PD(111);
D O I：
10.1002/cctc.201200033
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
[No abstract available]
引用
收藏
页码：1547 / 1550
页数：4
相关论文
共 24 条
[1]   HYDROGENATION OF ACETYLENE OVER SUPPORTED METAL-CATALYSTS .3. [C-14]-TRACER STUDIES OF THE EFFECTS OF ADDED ETHYLENE AND CARBON-MONOXIDE ON THE REACTION CATALYZED BY SILICA-SUPPORTED PALLADIUM, RHODIUM AND IRIDIUM [J].
ALAMMAR, AS ;
WEBB, G .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1979, 75 :1900-1911
[2]   Ru-Pt core-shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen [J].
Alayoglu, Selim ;
Nilekar, Anand U. ;
Mavrikakis, Manos ;
Eichhorn, Bryan .
NATURE MATERIALS, 2008, 7 (04) :333-338
[3]  
[Anonymous], 2005, ANGEW CHEM
[4]   STRUCTURAL REARRANGEMENTS IN CHEMISORBED HYDROCARBON LAYERS - 1,3-BUTADIENE ON RH/AL2O3 [J].
BASU, P ;
YATES, JT .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (05) :2028-2034
[5]   Adsorption-induced structural changes of Rh supported by TiO2(110)-(1x2):: An STM study [J].
Berkó, A ;
Solymosi, F .
JOURNAL OF CATALYSIS, 1999, 183 (01) :91-101
[6]   A comparative study of 1,3-butadiene and 1-butene chemisorbed on Pt(111), and Pd(111) [J].
Bertolini, JC ;
Cassuto, A ;
Jugnet, Y ;
Massardier, J ;
Tardy, B ;
Tourillon, G .
SURFACE SCIENCE, 1996, 349 (01) :88-96
[7]   Rhodium complex with ethylene ligands supported on highly dehydroxylated MgO: Synthesis, characterization, and reactivity [J].
Bhirud, VA ;
Ehresmann, JO ;
Kletnieks, PW ;
Haw, JF ;
Gates, BC .
LANGMUIR, 2006, 22 (01) :490-496
[8]   THE DELPLOT TECHNIQUE - A NEW METHOD FOR REACTION PATHWAY ANALYSIS [J].
BHORE, NA ;
KLEIN, MT ;
BISCHOFF, KB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (02) :313-316
[9]   HYDROGENATION OF UNSATURATED-HYDROCARBONS IN LIQUID-PHASE ON PALLADIUM, PLATINUM AND RHODIUM CATALYSTS .3. QUANTITATIVE SELECTIVITY RANKING OF PLATINUM, PALLADIUM AND RHODIUM IN THE HYDROGENATION OF 1-BUTENE, 1,3-BUTADIENE AND 1-BUTYNE USING A SINGLE REACTION SCHEME [J].
BOITIAUX, JP ;
COSYNS, J ;
ROBERT, E .
APPLIED CATALYSIS, 1987, 35 (02) :193-209
[10]   Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics [J].
Corma, Avelino ;
Serna, Pedro ;
Concepcion, Patricia ;
Juan Calvino, Jose .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8748-8753
123