The introduction of a perfluoroalkyl group, with emphasis on the trifluoromethyl moiety, is a challenging topic. Of the synthetic methods available in the repertoire of chemists, electrophilic introduction was until recently the least developed. In five years, however, a renaissance of this chemistry has happened. This renewal has been made possible thanks to reports both of numerous new reagents (stable, easy tohandle and to prepare) and of easier preparation of older reagents. Their availability rapidly inspired highly original works involving their use, in particular with the help of catalysis. This virtuous spiral, as well as all these exciting new developments, is described in this microreview.
机构:
Tianjin Univ, Dept Chem, Sch Sci, Tianjin 300072, Peoples R ChinaUniv Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
Ma, Jun-An
;
Cahard, Dominique
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Univ Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
INSA Rouen, F-76130 Mont St Aignan, FranceUniv Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
机构:
Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Mace, Yohan
;
Pradet, Charlotte
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机构:
GlaxoSmithKline, Synthet Chem, Stevenage SG1 2NY, Herts, EnglandUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Pradet, Charlotte
;
Popkin, Matthew
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机构:
GlaxoSmithKline, Synthet Chem, Stevenage SG1 2NY, Herts, EnglandUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Popkin, Matthew
;
Blazejewski, Jean-Claude
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Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Blazejewski, Jean-Claude
;
Magnier, Emmanuel
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h-index: 0
机构:
Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
机构:
Tianjin Univ, Dept Chem, Sch Sci, Tianjin 300072, Peoples R ChinaUniv Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
Ma, Jun-An
;
Cahard, Dominique
论文数: 0引用数: 0
h-index: 0
机构:
Univ Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
INSA Rouen, F-76130 Mont St Aignan, FranceUniv Mt St Aignan, CNRS, UMR 6014, Lab COBRA,IRCOF, F-76130 Mont St Aignan, France
机构:
Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Mace, Yohan
;
Pradet, Charlotte
论文数: 0引用数: 0
h-index: 0
机构:
GlaxoSmithKline, Synthet Chem, Stevenage SG1 2NY, Herts, EnglandUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Pradet, Charlotte
;
Popkin, Matthew
论文数: 0引用数: 0
h-index: 0
机构:
GlaxoSmithKline, Synthet Chem, Stevenage SG1 2NY, Herts, EnglandUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Popkin, Matthew
;
Blazejewski, Jean-Claude
论文数: 0引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
Blazejewski, Jean-Claude
;
Magnier, Emmanuel
论文数: 0引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, FranceUniv Versailles St Quentin en Yvelines, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France