Conversion of glucose into 5-hydroxymethylfurfural with WO3-MoO3 mixed metal oxides

被引：3

作者：

Du, Changhai ^{[1
]}

Zhang, Zhiwen ^{[1
]}

机构：

[1] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Jilin, Peoples R China

来源：

APPLIED ENERGY TECHNOLOGY, PTS 1 AND 2 | 2013年 / 724-725卷

关键词：

5-hydroxymethylfurfural; glucose; biphasic system; mixed metal oxides; CATALYST; BIOMASS; DEHYDRATION; FRUCTOSE; FURANS;

D O I：

10.4028/www.scientific.net/AMR.724-725.365

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

5-hydroxymethylfurfural (HMF) was produced from glucose using WO3-MoO3 mixed metal oxides as the catalyst in a biphasic system (H2O-NaCl/THF), comprised of reactive aqueous phase saturated with NaCl, and containing AlCl(3)6H(2)O, combined with an organic extracting phase consisting of tetrahydrofuran (THF). The influences of different catalysts, initial concentrations of glucose and reaction time on preparation of HMF were investigated. As a result, A HMF yield of 61% could be obtained at 170 degrees C in 40 min. Recycle of the aqueous phase and WO3-MoO3 demonstrated constant activity after 4 cycles of use.

引用

页码：365 / 368

页数：4

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