Probing Molecular Solids with Low-Energy Ions

被引：6

作者：

Bag, Soumabha ^{[1
]}

Bhuin, Radha Gobinda ^{[1
]}

Natarajan, Ganapati ^{[1
]}

Pradeep, T. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, DST Unit Nanosci, Madras 600036, Tamil Nadu, India

来源：

ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 6 | 2013年 / 6卷

关键词：

ice; mass spectrometry; soft landing; ion scattering; self-assembled monolayers; phase transition; GLASS-LIQUID TRANSITION; SURFACE-INDUCED DISSOCIATION; TEMPERATURE-PROGRAMMED DESORPTION; AMORPHOUS ICE FILMS; WATER-ICE; HYDROGEN-CHLORIDE; INFRARED-SPECTROSCOPY; CRYSTALLINE ICE; POLYATOMIC IONS; CHEMICAL-MODIFICATION;

D O I：

10.1146/annurev-anchem-062012-092547

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Ion/surface collisions in the ultralow- to low-energy (1-100-eV) window represent an excellent technique for investigation of the properties of condensed molecular solids at low temperatures. For example, this technique has revealed the unique physical and chemical processes that occur on the surface of ice, versus the liquid and vapor phases of water. Such instrument-dependent research, which is usually performed with spectroscopy and mass spectrometry, has led to new directions in studies of molecular materials. In this review, we discuss some interesting results and highlight recent developments in the area. We hope that access to the study of molecular solids with extreme surface specificity, as described here, will encourage investigators to explore new areas of research, some of which are outlined in this review.

引用

页码：97 / 118

页数：22

共 146 条

[1] Chemical modification of polystyrene surfaces by low-energy polyatomic ion beams [J].

Ada, ET ;

Kornienko, O ;

Hanley, L .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (20) :3959-3966

[2] Protons colliding with ice: Bouncing, sticking, splashing [J].

Al-Halabi, Ayman ;

Sanfelix, Pepa Cabrera ;

Holloway, Stephen ;

Kroes, Geert-Jan ;

Darling, George R. .

SURFACE SCIENCE, 2006, 600 (18) :4247-4250

[3] REACTIVE COLLISIONS OF POLYATOMIC IONS AT SOLID-SURFACES [J].

AST, T ;

MABUD, MA ;

COOKS, RG .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1988, 82 (1-2) :131-150

[4] Formation of H2+ by Ultra-Low-Energy Collisions of Protons with Water Ice Surfaces [J].

Bag, Soumabha ;

McCoustra, Martin R. S. ;

Pradeep, T. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (28) :13813-13819

[5] Ion beam source for soft-landing deposition [J].

Biesecker, JP ;

Ellison, GB ;

Wang, H ;

Iedema, MJ ;

Tsekouras, AA ;

Cowin, JP .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1998, 69 (02) :485-495

[6] INTERACTION OF CCL4 WITH THE SURFACE OF AMORPHOUS ICE [J].

BLANCHARD, JL ;

ROBERTS, JT .

LANGMUIR, 1994, 10 (09) :3303-3310

[7] Inducing H/D Exchange in Ultrathin Ice Films by Proton Deficiency [J].

Blomquist, J. ;

Andersson, M. P. ;

Uvdal, P. .

PHYSICAL REVIEW LETTERS, 2011, 107 (21)

[8] Reflection absorption infrared spectroscopy and temperature-programmed desorption studies of the adsorption and desorption of amorphous and crystalline water on a graphite surface [J].

Bolina, AS ;

Wolff, AJ ;

Brown, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (35) :16836-16845

[9] Cyanoacetylene adsorption on amorphous and crystalline water ice films: Instigation through matrix isolation and quantum study [J].

Borget, F ;

Chiavassa, T ;

Allouche, A ;

Marinelli, F ;

Aycard, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (43) :10668-10675

[10] REAL-TIME OPTICAL SPECTROSCOPY OF VACUUM ULTRAVIOLET IRRADIATED PYRENE: H2O INTERSTELLAR ICE [J].

Bouwman, J. ;

Paardekooper, D. M. ;

Cuppen, H. M. ;

Linnartz, H. ;

Allamandola, L. J. .

ASTROPHYSICAL JOURNAL, 2009, 700 (01) :56-62

← 1 2 3 4 5 6 7 8 9 10 →